Size and Shape Separation of Ag Nanoparticles by a Continuous Density Gradient Centrifugation

Article Preview

Abstract:

In order to get highly monodispersed nanoparticles, a post-synthesis separation of nanopaticles polydisersed in size and shape is often desired, although the experimental conditions for the synthesis of nanoparticles are carefully controlled. Using continuous density gradient centrifugation, Ag nanospheres, nanocubes, and nanowires can be separated from polydisperse samples. Size and dimension analysis by sanning electron microscopy and absorption spectroscopy prove that density gradient centrifugation is a powerful method to obtain monodisersed nanoparticles.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 560-561)

Pages:

728-731

Citation:

Online since:

August 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] M. Hanauer, S. Pierrat, I. Zins, A. Lotz, C. Sonnichsen, Separation of nanoparticles by gel electrophoresis according to size-and shape, Nano Lett. 79 (2007) 2881-2885.

DOI: 10.1021/nl071615y

Google Scholar

[2] A. M. Al-Somali, K. M. Krueger, J. C. Falkner, V. L. Colvin, Recycling size exclusion chromatography for the analysis and separation of nanocrystalline gold, Anal. Chem. 7619 (2004) 5903-5910.

DOI: 10.1021/ac049355h

Google Scholar

[3] S. F. Sweeney, G. H. Woehrle, J. E. Hutchison, Rapid purification and size separation of gold nanoparticles via diafiltration, J. Amer. Chem. Soc. 12810 (2006) 3190-3197.

DOI: 10.1021/ja0558241

Google Scholar

[4] L. Bai, X. J. Ma, J. F. Liu, X. M. Sun, D. Y. Zhao, D. G. Evans, Rapid Separation and Purification of Nanoparticles in Organic Density Gradients, J. Amer. Chem. Soc. 1327 (2010) 2333-2337.

DOI: 10.1021/ja908971d

Google Scholar

[5] X. J. Ma, Y. Kuang, L. Bai, Z. Chang, F. Wang, X. M. Sun, D. G. Evans, Experimental and Mathematical Modeling Studies of the Separation of Zinc Blende and Wurtzite Phases of CdS Nanorods by Density Gradient Ultracentrifugation, Acs Nano. 54 (2011).

DOI: 10.1021/nn200374t

Google Scholar

[6] X. Sun, S. Zaric, D. Daranciang, K. Welsher, Y. Lu, X. Li, H. Dai, Optical properties of ultrashort semiconducting single-walled carbon nanotube capsules down to sub-10 nm, J. Amer. Chem. Soc. 13020 (2008) 6551-6555.

DOI: 10.1021/ja8006929

Google Scholar

[7] B. Xiong, J. Cheng, Y. X. Qiao, R. Zhou, Y. He, E. S. Yeung, Separation of nanorods by density gradient centrifugation, J. Chromatogra. A. 121825 (2011)3823-3829.

DOI: 10.1016/j.chroma.2011.04.038

Google Scholar

[8] Y. Z. Lu, Y. C. Wang, W. Chen, Silver nanorods for oxygen reduction: Strong effects of protecting ligand on the electrocatalytic activity, J. Power Sources. 1966 (2011)3033-3038.

DOI: 10.1016/j.jpowsour.2010.11.119

Google Scholar

[9] Q. A. Zhang, W. Y. Li, C. Moran, J. Zeng, J. Y. Chen, L. P. Wen, Y. N. Xia, Seed-Mediated Synthesis of Ag Nanocubes with Controllable Edge Lengths in the Range of 30-200 nm and Comparison of Their Optical Properties, J. Amer. Chem. Soc. 13232 (2010).

DOI: 10.1021/ja104931h

Google Scholar

[10] V. Sharma, K. Park, M. Srinivasarao, Shape separation of gold nanorods using centrifugation, Proceedings of the National Academy of Sciences of the United States of America. 10613 (2009) 4981-4985.

DOI: 10.1073/pnas.0800599106

Google Scholar