A Continuous Process for the Preparation of Pyridine from Tetrahydrofurfuryl Alcohol with (MoO3-NiO) / Al2O3 as Catalyst

Lei Zhang; Shu Xian Meng; Ya Qing Feng; Bao Zhang; Zhe Xu

doi:10.4028/www.scientific.net/AMR.581-582.27

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 581-582A Continuous Process for the Preparation of...

A Continuous Process for the Preparation of Pyridine from Tetrahydrofurfuryl Alcohol with (MoO₃-NiO) / Al₂O₃ as Catalyst

Abstract:

Continuous synthesis of pyridine with (MoO₃-NiO) / Al₂O₃ has been developed. The doped NiO improved the dispersion of the MoO₃ particles and forms the new phase NiMoO₄ so that the Mo⁺⁶ particles were retained as the active sites. NiO also was found to have a great effect on the catalyst acidity. The reaction parameters were optimized and pyridine was obtained in a yield of 86.19%.

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Periodical:

Advanced Materials Research (Volumes 581-582)

Pages:

27-32

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.581-582.27

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Online since:

October 2012

Authors:

Lei Zhang, Shu Xian Meng, Ya Qing Feng, Bao Zhang, Zhe Xu

Keywords:

(MoO₃-NiO)/Al₂O₃, Amination, Cyclization, Pyridine, Tetradyrofurfuryl Alcohol

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