Target to Substrate Distance Dependent Optical and Electrical Properties of Sputtered NiO Films

Article Preview

Abstract:

Nickel oxide (NiO) thin films were deposited on glass substrates at various target to substrate distances in the range of 60 to 80 mm by dc reactive magnetron sputtering technique. It was observed that target to substrate distance influenced the morphological, optical and electrical properties of the deposited films. The optical results revealed that the optical transmittance of the films increased with increasing the target to substrate distance upto 70 mm, thereafter it was decreased. The increase in transmittance of the films was due to an increase in size of the grains. The NiO films exhibited an optical transmittance of 60 % and direct band gap of 3.82 eV at target to substrate distance of 70 mm. The films showed high electrical resistivity of 37.3 Ωcm at target to substrate distance of 60 mm and low electrical resistivity of 5.1 Ωcm at target to substrate distance of 70 mm. At high target to substrate distance of 80 mm the electrical resistivity of the film was increased.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

33-36

Citation:

Online since:

October 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] E. Fujji, A. Tomozawa, H. Torii, R. Takayama, Preferred orientations of NiO films prepared by plasma-enhanced metalorganic chemical vapor deposition, Jpn. J. Appl. Phys. 35 (1996) L328-L330.

DOI: 10.1143/jjap.35.l328

Google Scholar

[2] H. Sato, T.Minami, S. Takata, T. Yamada, Transparent conducting p-type NiO thin films prepared by magnetron sputtering, Thin Solid Films 236 (1993) 27-31.

DOI: 10.1016/0040-6090(93)90636-4

Google Scholar

[3] I.M. Chan, T.Y. Hsu, F.C. Hong, Enhanced hole injections in organic light-emitting devices by depositing nickel oxide on indium tin oxide anode, Appl. Phys. Lett. 81 (2002) 1899-1901.

DOI: 10.1063/1.1505112

Google Scholar

[4] D. Adler, J. Feinleib, Electrical and optical properties of narrow-band materials, Phy. Rev. B 2 (1970) 3112-3134.

DOI: 10.1103/physrevb.2.3112

Google Scholar

[5] K. Yoshimura, T. Miki, S. Tanemura, Nickel oxide electrochromic thin films prepared by reactive DC magnetron sputtering, Jpn. J. Appl. Phys. 34 (1995) 2440-2446.

DOI: 10.1143/jjap.34.2440

Google Scholar

[6] T. Seike, J. Nagai, Electrochromism of 3d transition metal oxides, Solar Energy Mater. 22 (1991) 107-117.

DOI: 10.1016/0165-1633(91)90010-i

Google Scholar

[7] T. Maruyama, S. Arai, The electrochromic properties of nickel oxide thin films prepared by chemical vapour deposition, Sol. Energy Mater. Sol. Cells 30 (1993) 257-262.

DOI: 10.1016/0927-0248(93)90145-s

Google Scholar

[8] J. A. Thornton, Influence of apparatus geometry and deposition conditions on the structure and topography of thick sputtered coatings, J. Vac. Sci. Technol. 11 (1974) 666-672.

DOI: 10.1116/1.1312732

Google Scholar

[9] P. Puspharajah, S. Radhakrishna, A.K. Arof, Transparent conducting lithium-doped nickel oxide thin films by spray pyrolysis technique, J. Mater. Sci. 32 (1997) 3001-3006.

DOI: 10.1023/a:1018657424566

Google Scholar

[10] E. Antolini, Sintering of LixMi1−xO solid solutions at 1200°C, J. Mater. Sci. 27 (1992) 3335-3340.

DOI: 10.1007/bf01116034

Google Scholar