X-Ray and Morphological Characterization of Al-O Thin Films Used for Vertically Aligned Single-Walled Carbon Nanotube Growth

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Abstract:

Al oxide (Al-O) films used as catalyst-support layer for vertical growth of carbon nanotubes (CNTs) were characterized by means of X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), transmission, and scanning electron microscopies (TEM and SEM). EB-deposited Al films (20 nm) were thermally-oxidized at 400 o C (10 min, static air) to produce the surface structure of Al-O. The Al-O was found amorphous and after the incorporation with Co catalyst, the grown CNTs were twisted together before vertically grown. The prepared Al-O surface is an electron-acceptor-dominated (oxygen-rich) surface where the formation of active catalyst could be enhanced to promote the vertically aligned CNT growth.

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[1] Y. Zhang, H. Feng, X. Wu, L. Wang, A. Zhang, T. Xia, H. Dong, X. Li and L. Zhang: Int. J. Hydrogen Energy 34 (2009) p.4889.

Google Scholar

[2] M. A. Azam, K. Isomura, A. Fujiwara and T. Shimoda: Global Engineers and Technologists Review 1 (2011) p.1.

Google Scholar

[3] M. A. Azam, M. A. Mohamed, E. Shikoh and A. Fujiwara: Jpn. J. Appl. Phys. 49 (2010) 02BA04.

Google Scholar

[4] H. Sugime and S. Noda: Carbon 48 (2010) p.2203.

Google Scholar

[5] M. A. Azam, A. Fujiwara and T. Shimoda: Appl. Surf. Sci. 258 (2011) pp.873-882.

Google Scholar

[6] Y. Rozita, R. Brydson and A. J. Scott: J. Phys. Conference Series 241 (2010) 012096.

Google Scholar

[7] F-H Lu, H-D Tsai and Y-C Chieh: Thin Solid Films 516 (2008) 1871.

Google Scholar

[8] H. Hongo, F. Niheya, T. Ichihashi, Y. Ochiai, M. Yudasaka and S. Iijima: Chem. Phys. Lett. 380 (2003) p.158.

Google Scholar

[9] F. Reichel, L. P. H. Jeurgens, G. Richter and E. J. Mittemeijer: J. Appl. Phys. 103 (2008) 093515.

Google Scholar

[10] M. A. Azam, A. Fujiwara and T. Shimoda: J. New Mat. Electrochem. Systems 14 (2011) pp.173-178.

Google Scholar

[11] J. Dijon: Carbon 48 (2010) p.3953.

Google Scholar

[12] M. R. Alexander, G. E. Thompson and G. Beamson, Surf. Interface Anal. 29 (2000) p.468.

Google Scholar

[13] A-C. Dupuis, Progress in Materials Science 50 (2005) p.929.

Google Scholar