Synthesis of Microcrystalline Cellulose Grafting Poly (methyl methacrylate) Copolymers by ATRP in 1-Allyl-3-Methylimidazolium Chloride

Er Jun Tang; Miao Yuan; Liang Li; Feng Bian; Di Shun Zhao

doi:10.4028/www.scientific.net/AMR.621.157

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Control on the Photoluminescence of ZnO Nanostructures Synthesized by a Reverse Micellar Route
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Synthesis of Microcrystalline Cellulose Grafting Poly (methyl methacrylate) Copolymers by ATRP in 1-Allyl-3-Methylimidazolium Chloride
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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 621Synthesis of Microcrystalline Cellulose Grafting...

Synthesis of Microcrystalline Cellulose Grafting Poly (methyl methacrylate) Copolymers by ATRP in 1-Allyl-3-Methylimidazolium Chloride

Abstract:

The microcrystalline cellulose grafting polymethylmethacrylate (MCC-g-PMMA) copolymer was successfully synthesized by atom transfer radical polymerization (ATRP) using ethanediamine as ligand in Ionic liquid 1-allyl-3-methylimidazolium chloride ([AMIM]Cl). The MCC-g-PMMA was characterized by FT-IR, 1H NMR, SEM and GPC spectroscopies. The results confirmed that the PMMA had been covalently bonded to cellulose backbone. The molecular weight of graft copolymers linearly increased during the polymerization and presented a low polydispersity.

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Periodical:

Advanced Materials Research (Volume 621)

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157-161

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.621.157

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Online since:

December 2012

Authors:

Er Jun Tang, Miao Yuan, Liang Li, Feng Bian, Di Shun Zhao

Keywords:

ATRP, Graft Copolymer, Ionic Liquid (IL), Microcrystalline Cellulose (MCC)

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