Synthesis of Ca(OH)2 Nanoparticles Aqueous Suspensions and Interaction with Silica Fume

Article Preview

Abstract:

In this work, interaction at ambient temperature between silica fume and artificially produced Ca(OH)2 nanoparticles by two different methods was analyzed. Initial products and formed hydrated phases were characterized by several investigations including X-ray diffraction, thermal analyses, transmission and scanning electron microscopy. Synthesized Ca(OH)2 nanoparticles appeared regularly shaped and hexagonally plated, with side dimensions from 200nm to less than 20nm. Characterization analyses showed that, by reducing particles dimensions, calcium silicate hydrate phase formation was evident already after 7 day of hydration and a nearly complete consuming of free Ca(OH)2 after 28 days was observed. Besides, formed hydrate phases showed a highly wrinkled layer with marked crumple and rough-edge surfaces.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

482-487

Citation:

Online since:

December 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Taylor HFW. The Chemistry of Cement, London, Academic Press; (1964).

Google Scholar

[2] Mitchell DRG, Hinczak I, Day RA. Interaction of Silica Fume with Calcium Hydroxide Solutions and Hydrated Cement Pastes, Cem. Concr. Res. 1998; 11, vol. 28: 1571-1584.

DOI: 10.1016/s0008-8846(98)00133-1

Google Scholar

[3] Baltakys K, Jauberthie R, Siauciunas R, Kaminskas R, Influence of modification of SiO2 on the formation of calcium silicate hydrate, Mater. Sci Poland 2007; 3, vol. 25: 663-670.

Google Scholar

[4] El-Shimy E et al. Physico-Chemical and Thermal Characteristics of Lime-Silica Fume Pastes, J. Therm. Anal. Calorim. 2000; 60: 549-556.

Google Scholar

[5] Huang CY, Feldman RF. Hydration reactions in Portland cement-silica fume blends, Cem. Concr. Res. 1985; 15: 585-592.

DOI: 10.1016/0008-8846(85)90056-0

Google Scholar

[6] Greenberg SA. Reaction between silica and calcium hydroxide solutions. Kinetics in the temperature range 30 to 85°. J. Phys. Chem. 1961; 65: 12-16.

DOI: 10.1021/j100819a005

Google Scholar

[7] Abo-El-Enein SA et al. Hydration of low porosity slag-lime pastes, Cem. Concr. Res. 1974; 4: 299-312.

DOI: 10.1016/0008-8846(74)90141-0

Google Scholar

[8] Abo-El-Enein SA, Shater MA, Nowar M. Il Cemento1981; 78: 137.

Google Scholar

[9] Abo-El-Enein SA et al.: ibid. 1990 ; 87: 147.

Google Scholar

[10] Mehta PK. Effect of lime on hydration of pastes containing gypsum and calcium aluminates or calcium sulfoaluminate, J. Am. Ceram. Soc. 1973; 56: 315-319.

DOI: 10.1111/j.1151-2916.1973.tb12503.x

Google Scholar

[11] Hekal EE. Effect of some admixture on the hydration of silica fume and hydrated lime, J. Mater. Sci. Technol. 2000; 4, vol. 16: 375-378.

Google Scholar

[12] Kondo R, Abo-El-Enein SA, Daimon M. Proc. 3rd Inter. Symp., . Aut. Calcium Silicate Build. Prods. Netherlands, p.25; Bull. Chem. Soc., Japan 1975; 48: 222.

Google Scholar

[13] Daniele V, Taglieri G, Quaresima R. The nanolimes in Cultural Heritage Conservation: characterisation and analysis of the carbonatation process, J. Cul. Her. 2008; 9: 294-301.

DOI: 10.1016/j.culher.2007.10.007

Google Scholar

[14] Daniele V, Taglieri G. Nanolime suspensions applied on natural lithotypes: the influence of concentration and residual water content on carbonatation process and on treatment effectiveness, J. Cul. Her. 2010; 11: 102-106.

DOI: 10.1016/j.culher.2009.04.001

Google Scholar

[15] Ambrosi M, Dei L, Giorgi R, Neto C, Baglioni P. Colloidal Particles of Ca(OH)2: Properties and Applications to Restoration of Frescoes, Langmuir 2001; 17: 4251-4255.

DOI: 10.1021/la010269b

Google Scholar

[16] Daniele V, Taglieri G. Synthesis of a nanolime by using Triton X-100 and protective treatments on natural stones: preliminary results, J. Cul. Her. 2012; 13: 40-46.

DOI: 10.1016/j.culher.2011.05.007

Google Scholar

[17] Ambrosi M, Giorgi R, Salvadori B, Dei L. Nanotecnologie per la conservazione di affreschi e materiali lapidei a base carbonatica, In: 1st International Workshop on Science, Technology and Cultural Heritage; Venezia, 29 Giugno – 1 Luglio; 2004: 29-33.

Google Scholar

[18] Lin RB et al. Characteristics and reactivities of Ca(OH)2/silica fume sorbents for low-temperature flue gas desulfurization, Chemical Engineering Science 2003; 58: 3659-3668.

DOI: 10.1016/s0009-2509(03)00222-7

Google Scholar