Preparation of Core-Shell Microspheres by Changing Reaction Solvent

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Abstract:

We have successfully prepared monodispersed core-shell microspheres with polystyrene cores and poly(N-isopropylacrylamide) shells by changing solvent from nonpolar to polar for the first time. Effects of stirring time and reaction temperature on the particle size, monodispersity of the microspheres were investigated. With increasing stirring time at 800 rpm, the size of the spheres and the monodispersity are the best when stirring time is 60 min. And with increasing reaction temperature (above phase transition), the size of the microspheres decreases and the monodispersity becomes better.

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Advanced Materials Research (Volumes 634-638)

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2242-2245

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January 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] Horak, D: Acta Polym. Vol. 47 (1996), p.20.

Google Scholar

[2] Y. Xia, B.Gates, Y. Yin and Y. Lu: Adv. Mater. Vol. 12 (2000), p.693.

Google Scholar

[3] J. Wang, P. A. G. Cormack, D. C. Sherrington and E. Khoshdel: Angew. Chem., Int. Ed. Vol. 42 (2003), p.5336.

Google Scholar

[4] L. Ye and K. Mosbach: Chem. Mater. Vol. 20 (2008), p.859.

Google Scholar

[5] L. Barner: Adv. Mater. Vol. 21 (2009), p.2547.

Google Scholar

[6] N. Nasongkla, E. Bey, J. Ren, H. Ai, C. Khemtong, J. S. Guthi, S. F. Chin, A. D. Sherry, D. A. Boothman and J. Gao: Micro. Letters Vol. 6 (2006), p.2427.

DOI: 10.1021/nl061412u

Google Scholar

[7] J. H. Gao, G. L. Liang, J. S. Cheung, Y. Pan, Y. Kuang, F. Zhao, B. Zhang, X. X. Zhang, E. X. Wu and B. Xu: J. Am. Chem. Soc. Vol. 130 (2008), p.11828.

Google Scholar

[8] J. Kim, H. S. Kim, N. Lee, T. Kim, H. Kim, T. Yu, I. C. Song, W. K. Moon and T. Hyeon: Angew. Chem., Int. Ed. Vol. 47 (2008), p.8438.

DOI: 10.1002/anie.200802469

Google Scholar

[9] J. S. Choi, Y.W. Jun, S.I. Yeon, H. C. Kim, J. S. Shin and J. Cheon: J. Am. Chem. Soc. Vol. 128 (2006), p.15982.

Google Scholar

[10] P. C. Angelomé, M. C. Fuertes and G. J. A. Soler-lllia: Adv. Mater. Vol. 18 (2006), p.2397.

Google Scholar

[11] J. Bao, W. Chen, T. T. Liu, Y. L. Zhu, P. Y. Jin, L. Y. Wang, J. F. Liu, Y. G. Wei and Y. D. Li: ACS Micro. Vol. 1 (2007), p.293.

Google Scholar

[12] Y. Okamoto, F. Kitagawa and K. Otsuka: Anal. Chem. Vol. 79 (2007), p.3041.

Google Scholar

[13] R. Contreras-Caceres, A. Sanchez-Iglesias, M. Karg, I. Pastoriza-Iglesias, J. Pérez-Juste, J. Pacifico, T. Hellweg, A. Fernández-Barbero and L.M. Liz-Marzán: Adv. Mater. Vol. 20 (2008), p.1666.

DOI: 10.1002/adma.200800064

Google Scholar

[14] R. A. Alvarez-Puebla, R. Contreras-Caceres, I. Pastoriza-Santos, J. Pérez-Juste and L. M. Liz-Marzán: Angew. Chem., Int. Ed. Vol. 48 (2009), p.138.

DOI: 10.1002/anie.200804059

Google Scholar

[15] C. Y. Liu, J. Guo, W. L.Yang, J. H. Hu, C. C. Wang and S. K. Fu: J. Mater. Chem. Vol. 19 (2009), p.4764.

Google Scholar

[16] N. Anton, J. P. Benoit and P. Saulnier: J. Control Release. Vol. 128 (2008), p.185.

Google Scholar

[17] Y. Chen, X. Lin, H. Park and R. Greever: Micromedicine Vol. 5 (2009), p.316.

Google Scholar

[18] P. Liu, G. F. Liu, W. Zhang and F. Jiang: Microtechnology Vol. 21 (2010), p.1.

Google Scholar

[19] F. Bai, X. L. Yang and W. Q. Huang: Macromolecules Vol. 37 (2004), p.9746.

Google Scholar

[20] O. H. Goncalves, J. M. Asua, P. H. H. Araűjo and R. A. F. Machado: Macromolecules Vol. 41 (2008), p.6960

Google Scholar

[21] J. H. Jiang, Y. Zhang, X. Z. Guo and H. Q. Zhang: Macromolecules Vol. 44 (2011), p.5893.

Google Scholar

[22] A. R. Shirin-Abadi, A. R. Mahdavian and S. Khoee: Macromolecules Vol. 44 (2011), p.7405.

Google Scholar