Synthesis and Crystal Structure of a Fe(II,III) Complex with 2-(4΄-Chlorine-benzoyl)-benzoic acid and 3-(2-Pyridyl)pyrazole

Qing Wei Wang; Ting Feng Lu; Jia Guo; Xiu Mei Li

doi:10.4028/www.scientific.net/AMR.634-638.2592

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 634-638Synthesis and Crystal Structure of a Fe(II,III)...

Synthesis and Crystal Structure of a Fe(II,III) Complex with 2-(4΄-Chlorine-benzoyl)-benzoic acid and 3-(2-Pyridyl)pyrazole

Abstract:

A new metal-organic complex FeII2FeIII2(cbba)4(L)6 (Hcbba = 2-(4΄-chlorine-benzoyl) benzoic acid, L = 3-(2-pyridyl)pyrazole) 1 has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, elemental analyses, TG and IR spectroscopy. The compound crystallizes in monoclinic, space group Cc with a = 17.729(5), b = 15.919(5), c = 33.650(5) Å, β = 92.058(5)°, V = 9491(4) Å3, C104H68Cl4Fe4N18O12, Mr = 2126.96, Dc = 1.489 g/cm3, μ(MoKα) = 0.786 mm1, F(000) = 4344, Z = 4, the final R = 0.0559 and wR = 0.1122 for 12093 observed reflections (I > 2(I)).

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Advanced Materials Research (Volumes 634-638)

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2592-2595

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https://doi.org/10.4028/www.scientific.net/AMR.634-638.2592

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January 2013

Authors:

Qing Wei Wang, Ting Feng Lu, Jia Guo, Xiu Mei Li

Keywords:

Crystal Structure, Hydrothermal Synthesis, Iron(II) Complex

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