Hydrothermal Synthesis and Crystal Structure of a Cadmium Complex

Shao Wei Tong; Jian Guo; Wen Dong Song; Jing Bo An

doi:10.4028/www.scientific.net/AMR.634-638.2600

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 634-638Hydrothermal Synthesis and Crystal Structure of a...

Hydrothermal Synthesis and Crystal Structure of a Cadmium Complex

Abstract:

A new coordination polymer based on cadmium nitrate and 2-（4-pyridyl-1H-benzimidazole- 5,6-dicarboxylate (H2pbd) , namely [Cd( pbd)2•(H2O)2]n•n(H2O)2, have been synthesized under hydrothermal conditions and characterized by elemental analysis, IR spectroscopy, and single crystal X-ray diffraction. The crystal of the complex crystallizes in triclinic, space group P-1 with a = 7.7200 Å, b = 8.1029Å, c = 13.0801Å, α= 96.1270(10) º, β = 102.1280(10)º, γ= 112.479(2) º, V = 723.15(12) Å3, Z =1, C28 H22 Cd N6 O12 and F(000) = 376.0. The H2pbd ligands links the Cd(II) atoms into a double stranded chain.

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Periodical:

Advanced Materials Research (Volumes 634-638)

Pages:

2600-2604

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.634-638.2600

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Online since:

January 2013

Authors:

Shao Wei Tong, Jian Guo, Wen Dong Song, Jing Bo An

Keywords:

2-(4-Pyridyl-1H-Benzimidazole-5,6-Dicarboxylate, Cadmium(II) Complex, Hydrothermal Synthesis

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