Paper Titles

Study on the Corrosion Performance of Reinforced Concrete by Using the Seawater Hot Rain Testing Equipment
p.173

Thermal Performance Analysis of the Molecular Linkers in the Carbon Nanotube Composites under Stress Conditions
p.179

Analysis of the Sequence Conservation of the Circadian Clock Protein KaiC
p.184

Effects of Vacuum Pre-Cooling on Quality of Mushroom after Cooling and Storage
p.189

Characterization of Fluorinated Multi-Walled and Single-Walled Carbon Nanotubes Using High Resolution XPS and EDX
p.194

Synthesis of Nimetazepam - Molecularly Imprinted Polymer and SPE Application
p.200

One-Step Effective Segregation of Ginger Essential Oil and Gingerol in Oleoresin Ginger via Transcritical CO₂
p.207

A New Process of Extracting Oleoresin Ginger from Ginger by Critical-State Liquid CO₂
p.212

Effect of Coal Moisture on Emissions in Fixed Bed Combustion Appliances
p.217

HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 699Characterization of Fluorinated Multi-Walled and...

Characterization of Fluorinated Multi-Walled and Single-Walled Carbon Nanotubes Using High Resolution XPS and EDX

Article Preview

Abstract:

Pristine and fluorinated multi-walled carbon nanotubes (MWCNTs) and single-walled carbon nanotubes (SWCNTs) were characterized using energy dispersive X-ray spectra (EDX) and X-ray photoelectron spectroscopy (XPS), respectively. The fluorine percentages of fluorinated multi-walled carbon nanotubes (F-MWCNTs) and fluorinated single-walled carbon nanotubes (F-SWCNTs) were 10.42% and 9.67% respectively by EDX. The absorption and de-absorption of fluorine properties were studied using high resolution C 1s and F 1s core level XPS and valence band spectra. The fluorine can be completely dissociated from F-MWCNTs, but partially dissociated from SWCNTs. There was 5.79% fluorine in atomic percent remaining associated with the F-SWCNTs when annealing the nanotubes to 500 °C measured by EDX. The results of F 1s core level XPS indicated that the binding energy of fluorine associated on SWCNTs was shifted from 687.0 eV to 688.3 eV after annealing the nanotubes to 500 °C. The results of valence band spectra showed that the binding energy of F 2p and F 2s shifted from 7.5 eV and 31.0 eV to 8.8 eV and 32.5 eV respectively in SWCNTS. However, the two peaks disappeared in annealed MWCNTs.

You might also be interested in these eBooks

Materials Science and Chemical Engineering

Info:

Periodical:

Advanced Materials Research (Volume 699)

Pages:

194-199

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.699.194

Citation:

Cite this paper

Online since:

May 2013

Authors:

Ling Zhi Sun, Xu Zhang

Keywords:

Carbon Nanotube (CN), EDX, High Resolution XPS, MWCNT, SWCNTs

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] S. Iijima, Nature, 1991. 354: pp.56-58.

[2] GAO Quan-yong, Z.J., YANGYong, Journal of Electrochemistry, 2005. 11(01): pp.87-91.

[3] Nathan S. Lawrence, R.P.D., Joseph Wang, Electroanalysis, 2004. 17(1): pp.65-72.

[4] Musameh, J.W.a.M., Analytica chimica acta, 2004. 511(1).

[5] Joseph Wang, A.-N.K.a.M.M., Analyst, 2003. 128: pp.912-16.

[6] E. Frackowiak, K.M., V. Bertagna, and F. Beguin, Appl. Phys. Lett., 2000. 77(15): pp.2421-3.

[7] Jean-Marc Bonard, M.C., Christian Klinke, Ralph Kurt1, Olivier Noury, Nicolas Weiss, carbon, 2002. 40(10): pp.1715-28.

[8] YS Anito, J Nanosci Nanotechnol., 2003. 3(1-2): pp.39-50.

[9] Chaniotakis, S.S.N.A., Anal bioanal chem., 2003. 375: pp.103-05.

[10] Wang, J., Electroanalysis, 2004. 2005(1): pp.7-14.

[11] Ane Jensen, J.R.H., Jesper Nygård, Janusz Sadowski, Poul Erik Lindelof, Nano Letters, 2004. 4(2): pp.349-52.

[12] Qing Cao, H.-s.K., Ninad Pimparkar, Jaydeep P. Kulkarni, Congjun Wang, Moonsub Shim, Kaushik Roy, Muhammad A. Alam & John A. Rogers, nature, 2008. 454: pp.495-500.

DOI: 10.1038/nature07110

[13] E. Heister, V.N., T. Carmen, et al., Carbon, 2009. 47: pp.2152-2160

[14] Jabr-Milane, L.S., et al., Cancer Treat Rev, 2008. 34(7): pp.592-602.

[15] Dhar, S., et al., J Am Chem Soc, 2008. 130(34): pp.11467-76.

[16] Zhuang L, S.X.M., Nakayama-Ratchford N., Dai H.J. , ACS Nano, 2007(1): pp.50-56.

[17] Singh, R., et al., J Am Chem Soc, 2005. 127(12): pp.4388-96.

[18] Kam, N.W. and H. Dai, J Am Chem Soc, 2005. 127(16): pp.6021-6.

[19] Kam, N.W., et al., Proc Natl Acad Sci U S A, 2005. 102(33): pp.11600-5.

[20] Peer, D., et al., Nat Nanotechnol, 2007. 2(12): pp.751-60.

[21] Malhotra, R., et al., Anal Chem. 82(8): pp.3118-23.

[22] Yu, X., et al., J Am Chem Soc, 2006. 128(34): pp.11199-205.

[23] Jensen, G.C., et al., J Nanosci Nanotechnol, 2009. 9(1): pp.249-55.

[24] Bhirde, A.A., et al., ACS Nano, 2009. 3(2): pp.307-16.

[25] Sinha, N. and J.T. Yeow, IEEE Trans Nanobioscience, 2005. 4(2): pp.180-95.

[26] Zhang, X., et al., Biomaterials, 2009. 30(30): pp.6041-7.

[27] Chen, J., et al., J Am Chem Soc, 2008. 130(49): pp.16778-85.

[28] Panyam, J. and V. Labhasetwar, Adv Drug Deliv Rev, 2003. 55(3): pp.329-47.

[29] Kam, N.W., Z. Liu, and H. Dai, J Am Chem Soc, 2005. 127(36): pp.12492-3.

[30] Liu, Z., et al., Angew Chem Int Ed Engl, 2007. 46(12): pp.2023-7.

[31] Rusling, J.F., et al., Analyst. 135(10): pp.2496-511.

[32] Bi, S., H. Zhou, and S. Zhang, Biosens Bioelectron, 2009. 24(10): pp.2961-6.

[33] Lam, C.W., et al., Crit Rev Toxicol, 2006. 36(3): pp.189-217.

[34] Firme, C.P., 3rd and P.R. Bandaru, Nanomedicine. 6(2): pp.245-56.

[35] Zhang X, Zhang W.D., Liu L., Shen Z.X., 2003. Chem. Phys. Lett (372): pp.497-502.