Nanostructured Graphenes and Metal Oxides for Fuel Cell and Battery Applications

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Graphene/spacer nanoparticle composites were prepared by reducing graphene oxide with hydrazine in the presence of different contents of polyaniline nanoparticles. In-situ cryo-TEM image of GO-spacer solution shows that spacer nanoparticles are anchored on GO sheets. During the reduction, as-adsorbed spacer nanoparticles were sandwiched between layers of graphene. These spacer nanoparticles act as spacers to create gaps between neighboring graphene sheets, resulting in higher surface area. Graphene/spacer nanocomposites exhibited highest specific surface area of 1500 m2/g. Utilizing this composite material, a supercapacitor with specific capacitance of 267 F/g at a current density of 0.1 A/g was achieved.

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126-131

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June 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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