Effects of the Chemical Compositions of KF-CsF-AlF3 Middle Temperature Aluminum Flux on Melting Characteristics

Article Preview

Abstract:

According to the KF-CsF-AlF3 ternary phase diagram, 25 samples (named group A) near the region around the E4 and E5 (ternary eutectics points), and 22 samples (named group B) near another region around the e5 (binary eutectic point) and m2 (ternary eutectics point) were prepared by the wet synthesis method. The melting curves of these samples were measured by differential scanning calorimetry (DSC). Based on the DSC data, the effects of the fluxs compositions on the melting characteristics were analyzed and summarized. The results indicated that the lowest solidus of group A samples was about 480°C, meanwhile, their liquidus was about 520~530°C, and the melting range was approximately 40°C. Furthermore, when the content of CsF was lower than 18mol%, the solidus of group A samples apparently rose to about 510°C, but the liquidus did not change greatly. The lowest solidus of group B samples was about 420°C, meanwhile, their liquidus was below 450°C, and the melting range was approximately 20~30°C. So, with this profile of melting characteristics, some of the samples of group B flux would be good substrates for aluminum alloy middle temperature brazing, with good prospects for application.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

191-198

Citation:

Online since:

July 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Zhang Qiyun, Zhuang Hongshou. Brazing and Soldering Manual. Second Edition. Beijing: China Machine Press, 2008, p.45 (in Chinese).

Google Scholar

[2] Cai Zhihong, He Junsi, Yang Zhanhong, et al. Welding Technology. 2009,38(1), 3-6(in Chinese).

Google Scholar

[3] Dai Wei, Xue Songbai, Lou Jiyuan, et al. Transactions of Nonferrous Metals Society of China. 2012,22,30-35.

Google Scholar

[4] Cai Zhihong, He Junsi, Yang Zhanhong, et al. Welding Equipment and Materials. 2011,40(2):39-42 (in Chinese).

Google Scholar

[5] Jia Hu, Qiyun Zhang. Thermochimica Acta. 2003, 404:3-7.

Google Scholar

[6] Chen R., Zhang Q. Thermochimica Acta. 1999, 335:117.

Google Scholar

[7] Chen R., Zhang Q. . Thermochimica Acta. 2000, 354:117.

Google Scholar

[8] Chen R., Zhang Q. Solid State Chem. 2001, 161:80.

Google Scholar

[9] Guangzhou Res. Inst. Nonferrous Metals. Studies on Preparation Process and Application of Potassium Fluoaluminate Flux by Chemical Synthesis Method[R]. Guangzhou: Guangzhou Res. Inst. Nonferrous Metals, 1995 (in Chinese).

Google Scholar

[10] Zhang Qiyun. Advanced Inorganic Chemistry Experiment. Beijing: Peking University Press, 1987, 130-143(in Chinese).

Google Scholar

[11] Chen R., Gao J., Zhang Q. Thermochimia Acta. 1997, 303:145.

Google Scholar