Facile, Alternative Synthesis of Spherical-Like Ca(H2PO4)2•H2O Nanoparticle by Aqueous-Methanol Media

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Abstract:

Spherical-like calcium dihydrogenphosphate monohydrate (Ca (H2PO4)2H2O) nanostructure was successfully prepared by the mixing of calcium carbonate and phosphoric in aqueous-methanol media at ambient temperature for 30 min. Three thermal decomposition step and higher stability at over 800 °C of the prepared sample are different from the earlier works. Spherical-like Ca (H2PO4)2H2O nanostructure with diameter < 100 nm confirmed by SEM may be important for potential applications. This method of synthesis by aqueous-methanol media is a fast and simple method and it is expected to be applicable for the synthesis of other nanocrystalline calcium phosphates.

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49-53

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July 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] I. S. Neira, Y. V. Kolen'ko, O.I. Lebedev, G. V. Tendeloo, H. S. Gupta, N. Matsushita, M. Yoshimura, F. Guitián, Mater. Sci. Eng: C, vol. 29, (2009), pp.2124-2132.

Google Scholar

[2] S. R. Paital and N. B. Dahotre, Mater. Sci. Eng: R: Reports, vol. 66, (2009), pp.1-70.

Google Scholar

[3] M. Vallet-Regí and J. M. González-Calbet, Prog. Solid State Chem. vol. 32, (2004), pp.1-31.

Google Scholar

[4] D. Jiang and J. Zhang, Curr. Appl. Phys, vol. 9, (2009), pp. S252-S256.

Google Scholar

[5] E. Beniash, R. A. Metzler, R.S.K. Lam and P.U.P.A. Gilbert, J. Struct. Biol., vol.166, (2009), pp.133-143.

Google Scholar

[6] B. Li, X.Chen, B.o Guo, X.Wang, H. Fan and X. Zhang, Acta Biomater. vol.5, (2009), pp.134-143.

Google Scholar

[7] N. Rameshbabu and K. Prasad Rao, Curr. Appl. Phys., vol.9, (2009), pp. S29-S31.

Google Scholar

[8] C. E. Pedraza, D. C. Bassett, M. D. McKee, V. Nelea, U. Gbureck and J. E. Barralet, Biomaterials, vol.29, (2008), pp.3384-3392

DOI: 10.1016/j.biomaterials.2008.04.043

Google Scholar

[9] S. Singh, P. Bhardwaj, V. Singh, S. Aggarwal and U.K. Mandal, J. Colloid Interface Sci. vol.319, (2008), .pp.322-329

Google Scholar

[10] C. Liang, Z. Li, D. Yang, Y.Li, Z. Yang and W. W. Lu, Mater. Chem. Phys. vol.88, (2004) pp.285-289.

Google Scholar

[11] L. Gan and R. Pilliar, Biomaterials, vol. 25, (2004), pp.5303-5312.

Google Scholar

[12] Q.-L. Tang, K.-W. Wang, Y.-J. Zhu and F. Chen, Materials Letters, vol.63, (2009), pp.1332-1334.

Google Scholar

[13] R. Xin, F. Ren and Y. Leng, Materials & Design. vol. 31, no. 4, (2010), pp.1691-1694.

Google Scholar

[14] K. Fukui, S. Kidoguchi, N. Arimitsu, K. Jikihara, T.Yamamoto and H. Yoshida, J. Env. Manag, vol.90, (2009), pp.2709-2714

Google Scholar

[15] K. C. B. Yeong, J. Wang and S. C. Ng, Biomaterials, vol. 22, (2001), pp.2705-2712.

Google Scholar

[16] K. Jamuna-Thevi, F.A. Zakaria, R. Othman and S. Muhamad, Mater. Sci. Eng. C, vol. 29, (2009), pp.1732-1740.

Google Scholar

[17] B. Boonchom, C. Danvirutai and S. Maensiri, Mater. Chem.Phys., vol.109, (2008), pp.404-410.

Google Scholar

[18] C. Danvirutai, B. Boonchom and S.Youngme, J. Alloys Compds, vol.457, (2008), pp.75-80.

Google Scholar

[19] B. Boonchom, S. Youngme, S. Maensiri, and C. Danvirutai, J. Alloys Compds, vol.454, (2008), pp.78-82.

Google Scholar

[20] B. Boonchom, J. Alloys Compds, vol. 482, (2009), pp.199-202.

Google Scholar

[21] S. Scaccia, M. Carewska, A. Di Bartolomeo and P. P. Prosini, Thermochim. Acta, vol.397, (2003), pp.135-141.

Google Scholar

[22] Y. Han, S. Li, X. Wang, L. Jia and J. He, Mater. Res. Bull. Vol.42, (2007), p.1169.-1177.

Google Scholar

[23] B.D. Cullity, Elements of X-ray Diffraction, second ed., Addison-Wesley Publishing, 1977.

Google Scholar

[24] C.-K. Hsu, Mater. Chem. Phys. vol.80, (2007), pp.409-420.

Google Scholar

[25] A. Ioiţescu, G. Vlase, T. Vlase and N. Doca, J. Therm. Anal. Calorim. Vol. 88, (2007), pp.121-125.

DOI: 10.1007/s10973-006-8022-3

Google Scholar

[26] J. Xu, D. F.R. Gilson and I. S. Butler, Spectrochim. Acta A, vol.54, (1998), p.1869–1878.

Google Scholar