Base-Catalyzed Transesterification of Soybean Oil by Ultrasonication

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Abstract:

Biodiesel is a renewable, biodegradable, and nontoxic fuel. At present, biodiesel is primarily produced in batch reactors in which the required energy is provided by heating accompanied by mechanical mixing. Alternatively, ultrasonic processing is an effective way to attain required mixing while providing the necessary activation energy. Biodiesel was synthesized by soybean oil using ultrasonication and alkali-acid catalysis method. Its structure was characterized by gas chromatograph, and the effects of various factors on transesterification rate were studied. The results show that a biodiesel yield in excess of 97% can be achieved in 30 min, methanol/oil molar ratio of 6:1, 1% of alkaline.

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Advanced Materials Research (Volumes 724-725)

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356-359

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August 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] Ma, F.; Hanna, M. A. Biodiesel production: A review. Bioresour. Technol. 1999, 70, 1-15.

Google Scholar

[2] Schuchardt, U.; Sercheli, R.; Vargas, R. M. Transesterification of vegetable oils: A review. J. Braz. Chem. Soc. 1998, 9 (1), 199-210.

DOI: 10.1590/s0103-50531998000300002

Google Scholar

[3] Benitez, F. A. Effect of the use of ultrasonic waves on biodiesel production in alkaline transesterification of bleached tallow and vegetable oils: cavitation model. Dissertation, University of Puerto Rico,Mayaguez, Puerto Rico, 2004.

Google Scholar

[4] Stavarache, C.; Vinatoru, M.; Nishimura, R.; Maeda, Y. Conversion of vegetable oil to biodiesel using ultrasonic irradiation. Chem. Lett. 2003, 32 (8), 716-717.

DOI: 10.1246/cl.2003.716

Google Scholar

[5] Stavarache, C.; Vinatoru, M.; Nishimura, R.; Maeda, Y. Fatty acids methyl esters from vegetable oil by means of ultrasonic energy. Ultrason. Sonochem. 2005, 12 (5), 367-372.

DOI: 10.1016/j.ultsonch.2004.04.001

Google Scholar

[6] Shah, S.; Sharma, A.; Gupta, M. N. Extraction of oil from Jatrophe curcas L. seed kernels by combination of ultrasonication and aqueous enzymatic oil extraction. Bioresour. Technol. 2005, 96, 121-123.

DOI: 10.1016/j.biortech.2004.02.026

Google Scholar

[7] Zullaikah, S., Lai, C. C., Vali, S. R., Ju, Y. H., A two-step acid-catalyzed process for the production of biodiesel from rice bran oil. Bioresour. Technol. 2005, 96, 1889–1896.

DOI: 10.1016/j.biortech.2005.01.028

Google Scholar