Synthesis, Structures and Properties of Two New Three-Dimensional Ce(III) Coordination Polymers with 2,2'-Bipyridine-4,4'-Dicarboxylic Acid

Rui Ping Zheng; Hui Yuan Chen; Jun Jie He; He Ping Zeng

doi:10.4028/www.scientific.net/AMR.750-752.1708

Paper Titles

Carbonization Regime Process of Coal Tar Refined Soft Pitch
p.1689

TiO₂ Nanotube Film as the Support of Platinum Electro-Catalyst with Enhanced Electrochemical Activity for Methanol Oxidation
p.1696

Effects of Carriers on Amination of Ethanol to Acetonitrile over Catalysts Loaded with Cu
p.1700

Numerical Simulation on the Preparation of Vinyl Acetate Catalyst in Fluidized Bed
p.1704

Synthesis, Structures and Properties of Two New Three-Dimensional Ce(III) Coordination Polymers with 2,2'-Bipyridine-4,4'-Dicarboxylic Acid
p.1708

Experimental Investigation on Coking Characteristics of China RP-3 Kerosene under High Temperature and Long-Duration Conditions
p.1712

Modelling of a Monolithic Solid Oxide Fuel Cell
p.1718

Analysis of Nitrogen Oxides Formation in CH₄/Air Laminar Premixed Flame
p.1734

Adsorption Property of MgAl-NO₃ Layered Double Hydroxides to Methyl Orange
p.1738

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 750-752Synthesis, Structures and Properties of Two New...

Synthesis, Structures and Properties of Two New Three-Dimensional Ce(III) Coordination Polymers with 2,2'-Bipyridine-4,4'-Dicarboxylic Acid

Abstract:

Two new Ce(III) coordination polymers formulated as Ce(bpdc)(Hbpdc)(DMF)2 (1) and [Ce2(bpdc)3(DMF)2(H2O)4]·2DMF (2) (H2bpdc = 2,2'-bipyridine-4,4'-dicarboxylic acid, DMF = N,N-Dimethyl formamide) have been synthesized under solvothermal condition and characterized by single-crystal X-ray diffraction. Compound 1 crystallizes in monoclinic, space group C2/c with a = 2.2520(2), b = 1.17787(12), c = 1.16128(11) nm, α = 90, β = 95.5600(10), γ = 90°, V = 3.0658(5) nm3, Z = 4, Mr = 771.70, Dc = 1.672×10-9 g/cm3. Compound 2 crystallizes in triclinic, space group Pwith a = 1.00610(10), b = 1.17219(11), c = 1.36891(14) nm, α = 66.9340(10), β = 87.182(2), γ = 76.2570(10) °, V = 1.4411(2) nm3, Z = 1, Mr = 1371.25, Dc = 1.580×10-9 g/cm3. Both compounds exhibit 3D Ce(III)–organic frameworks. Furthermore, thermal stability and luminescent properties were also investigated. CCDC:(1)913670, (2)909563.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 750-752)

Pages:

1708-1711

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.750-752.1708

Citation:

Cite this paper

Online since:

August 2013

Authors:

Rui Ping Zheng*, Hui Yuan Chen, Jun Jie He, He Ping Zeng

Keywords:

Bipyridine Dicarboxylic Acid, Ce(III) Coordination Polymer, Crystal Structure

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] Chen, K.; Dong, D. P.; Sun, Z. G.; Jiao, C. Q.; Li, C.; Wang, C. L.; Zhu, Y. Y.; Zhao, Y.; Zhu, J.; Sun,S. H.; Zheng, M. J.; Tian, H.; Chu, W. Dalton Trans. (2012), 41, 10948-10956.

DOI: 10.1039/c2dt30363a

Google Scholar

[2] Feng, R.; Jiang, F. L.; Wu, M. Y.; Chen, L.; Yan, C. F.; Hong, M. C. Cryst. Growth & Des. (2010), 10, 2306-2313.

Google Scholar

[3] Shi, P. F.; Chen, Z.; Xiong, G.; Shen, B.; Sun, J. Z.; Cheng, P.; Zhao, B. Structures, Cryst. Growth & Des. (2012), 12, 5203-5210.

Google Scholar

[4] Tan, Y. X.; Wang, F.; Kang, Y.; Zhang, J. Chem. Commun. (2011), 47, 770-772.

Google Scholar

[5] Liu, M. S.; Yu, Q. Y.; Cai, Y. P.; Su, C. Y.; Lin, X. M.; Zhou, X. X.; Cai, J. W. Cryst. Growth & Des. (2008), 8, 4083–4091.

Google Scholar

[6] Mikaela, G.; Su, J.; Yue, H. J.; Yao, Q. X.; Zou, X. D. Cryst. Growth & Des. (2012), 12, 3243-3249.

Google Scholar

[7] Wang, C. C.; Wang, Z. H.; Gu, F. B.; Guo, G. S. J. Mol. Struct. (2010), 979, 92–100.

Google Scholar

[8] Yan, S. H.; Zheng, X. J. J. Mol. Struct. (2010), 964, 52–57.

Google Scholar

[9] Sheldrick, G. M. SHELXS97. Program for the Solution of Crystal Structure. Göttingen University, Germany (1997).

Google Scholar

[10] Sheldrick, G. M. SHELXL97. Program for the Refinement of Crystal Structure. Göttingen University, Germany (1997).

Google Scholar