Synthesis and Characterization of PANI/Ferric Chloride Composite for Fabrication of Electrodes in Supercapacitor

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The main objective of this work is to synthesize polyaniline/ferric chloride composite and to measure the conductivity of the as prepared composite. And also, to analyze the ability of using Ferric Chloride doped polyaniline as an electrode material for the fabrication of supercapacitor application. By in-situ polymerization method, polyaniline in pure form and doped form with the ferric chloride were synthesized using ammonium persulfate as initiator in HCl medium. Polyaniline nanoparticles and its composite are characterized by UV-Vis spectroscopy, FTIR, XRD and Conductivity meter.

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334-337

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September 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] M. Jayalakshmi and K. Balasubramanian, Simple Capacitors to Supercapacitors - An Overview, International Journal of Electrochemical Science, Vol. 3, p.1196 – 1217, (2008).

Google Scholar

[2] Xiaoxia Xiang, Enhui Liu, Zhengzheng Huang, Haijie Shen, Yingying Tian, Chengyi Xiao, Jingjing Yang and Zhaohui Mao, Preparation of activated carbon from polyaniline by zinc chloride activation as supercapacitor electrodes, J Solid state Electrochem., Vol. 15, p.2667–2674, (2011).

DOI: 10.1007/s10008-010-1258-7

Google Scholar

[3] R. S. Hastak, P. Sivaraman, D. D. Potphode, K. Shashidhara and A. B. Samui, High temperature all solid state supercapacitor based on multi-walled carbon nanotubes and poly[2, 5 benzimidazole], J Solid State Electrochem., (2012).

DOI: 10.1007/s10008-012-1679-6

Google Scholar

[4] Li JianLing, Gao Fei, Zhang YaKun, Kang FeiYu, Wang XinDong, Ye Feng and Yang Jun, Electropolymerization of Ni(salen) on carbon nanotube carrier as a capacitive material by pulse potentiostatic method, Sci China Chem., Vol. 55, No. 7, p.1338–1344, July (2012).

DOI: 10.1007/s11426-012-4585-y

Google Scholar

[5] Hossein Farsi, Fereydoon Gobal and Zahra Barzgari, A study of hydrated nanostructured tungsten trioxide as an electroactive material for pseudocapacitors, Ionics, (2012).

DOI: 10.1007/s11581-012-0726-8

Google Scholar

[6] Zhiyi Lu, Qiu Yang, Wei Zhu, Zheng Chang, Junfeng Liu, Xiaoming Sun, David G. Evans and Xue Duan, Hierarchical CoO@Ni–Co–O Supercapacitor Electrodes with Ultrahigh Specific Capacitance per Area, Nano Res., 5(5): p.369–378, (2012).

DOI: 10.1007/s12274-012-0217-2

Google Scholar

[7] Shuangling Guo, Fang Wang, Hao Chen, He Ren, Rongshun Wang and Xiumei Pan, Preparation and performance of polyvinyl alcohol-based activated carbon as electrode material in both aqueous and organic electrolytes, Journal of Solid State Electrochemistry, (2012).

DOI: 10.1007/s10008-012-1779-3

Google Scholar

[8] Y. N. Sudhakar, M. Selvakumar and D. Krishna Bhat, LiClO4-doped plasticized chitosan and poly(ethylene glycol) blend as biodegradable polymer electrolyte for supercapacitors, Ionics, (2012).

DOI: 10.1007/s11581-012-0745-5

Google Scholar

[9] M. P. Karushev and A. M. Timonov, Adsorption-Electrochemical Modification of Nanoporous Carbon Materials by Nickel Complexes with Schiff Bases, Russian Journal of Applied Chemistry, Vol. 85, No. 6, p.914−920, (2012).

DOI: 10.1134/s1070427212050134

Google Scholar

[10] Stefano Mezzavilla, Caterina Zanella, Parakkulam Ramaswamy , Claudio Della Volpe and Gian Domenico Soraru, Carbon xerogels as electrodes for supercapacitors. The influence of the catalyst concentration on the microstructure and on the electrochemical properties, J Mater Sci., (2012).

DOI: 10.1007/s10853-012-6662-1

Google Scholar

[11] Saptarshi Dhibar, Sumanta Sahoo, C. K. Das, R. Singh, Investigations on copper chloride doped polyaniline composites as efficient electrode materials for supercapacitor applications, Journal of Materials Science: Materials in Electronics, (2012).

DOI: 10.1007/s10854-012-0800-z

Google Scholar

[12] L. V. Morozova, T. I. Panova, V. P. Popov, I. N. Tsvetkova, and O. A. Shilova, Synthesis and Study of Oxide and Phosphor–Silicate Nanocomposites for the Creation of New-Generation Supercapacitors, Glass Physics and Chemistry, Vol. 38, No. 3, p.332–338, (2012).

DOI: 10.1134/s1087659612030121

Google Scholar

[13] Kalimuthu Vijaya Sankar, D. Kalpana, Ramakrishnan Kalai Selvan, Electrochemical properties of microwave-assisted reflux-synthesized Mn3O4 nanoparticles in different electrolytes for supercapacitor applications, J Appl Electrochem., Vol. 42, p.463–470, (2012).

DOI: 10.1007/s10800-012-0424-2

Google Scholar

[14] Rixiong Chen, Shuhui Yu, Rong Sun, Wenhu Yang and Yubao Zhao, KCl-assisted, chemically reduced graphene oxide for high-performance supercapacitor electrodes, Journal of Solid State Electrochemistry, (2012).

DOI: 10.1007/s10008-012-1796-2

Google Scholar

[15] Xiwen Wang, Suqin Liu, Haiyan Wang, Feiyue Tu, Dong Fang and Yanhua Li, Facile and green synthesis of Co3O4nanoplates/graphene nanosheets composite for supercapacitor, J Solid State Electrochem., (2012).

DOI: 10.1007/s10008-012-1744-1

Google Scholar

[16] Liang QingQin, Li YueMing and Li JingHong, Low temperature synthesis of NiO/Co3O4 composite nanosheets as high performance Li-ion battery anode materials, Chinese Science Bulletin, (2012).

DOI: 10.1007/s11434-012-5290-0

Google Scholar

[17] Fang Jing, Cui Mu, Lu Hai, Zhang Zhi-an, Lai Yan-qing and Li Jie, Hybrid supercapacitor based on polyaniline doped with lithium salt and activated carbon electrodes, Journal of Central South University of Technology, Vol. 16, p.0434−0439, (2009).

DOI: 10.1007/s11771-009-0073-8

Google Scholar

[18] Majid Beidaghi, Zhifeng Wang, Lin Gu and Chunlei Wang, Electrostatic spray deposition of graphene nanoplatelets for high-power thin-film supercapacitor electrodes, J Solid State Electrochem., (2012).

DOI: 10.1007/s10008-012-1777-5

Google Scholar

[19] Chongyong Ge, Zhaohui Hou, Binhong He, Fanyan Zeng, Jianguo Cao, Yiming Liu and Yafei Kuang, Three-dimensional flower-like nickel oxide supported on graphene sheets as electrode material for supercapacitors, J Sol-Gel Sci Technol., Vol. 63, p.146–152, (2012).

DOI: 10.1007/s10971-012-2778-7

Google Scholar

[20] Wen ChunMing, Wen ZhiYu, You Zheng and Wang XiaoFeng3, Preparation and characterization of three-dimensional micro-electrode for micro-supercapacitor based on inductively coupled plasma reactive etching technology, Science China Technological Sciences, Vol. 55, No. 7, p.2013–2018, July (2012).

DOI: 10.1007/s11431-012-4869-7

Google Scholar