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Preparation and Mechanism of Spherical [Ni1/3Co1/3Mn1/3]Ox Precursors for Li [Ni1/3Co1/3Mn1/3]O2 by an Ultrasonic Atomization Method

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Abstract:

The spherical precursors - [Ni1/3Co1/3Mn1/3]Ox and Li [Ni1/3Co1/3Mn1/3]O2 were synthesized by an ultrasonic atomization method via two routes. The [Ni1/3Co1/3Mn1/3]Ox and Li [Ni1/3Co1/3Mn1/3]O2 powders were characterized by means of X-ray diffraction (XRD) and scanning electron microscopy (SEM). The experimental results show that the initial concentration of the raw solution would affect the size of precursor [Ni1/3Co1/3Mn1/3]Ox particles. The Li [Ni1/3Co1/3Mn1/3]O2 particles which were prepared from the mixture of LiNO3 and [Ni1/3Co1/3Mn1/3]Ox were much larger than the precursor particles and those prepared from the LiNO3-[Ni1/3Co1/3Mn1/3]Ox may maintain the size of the precursor particles.

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Periodical:

Advanced Materials Research (Volume 773)

Pages:

572-579

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.773.572

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Online since:

September 2013

Authors:

Qing Lin Chen, Xue Wen Liu, Bao Hua Rong, Kun Tang, Hua Zhen Yang, Yan Wen Lu, Xing Yun Wu, Fei Shen, Yue Feng Tang, Yan Feng Chen

Keywords:

Cathode Material, Lithium-Ion Battery, Spherical Li[Ni1/3Co1/3Mn1/3]O2 Precursors, Ultrasonic Atomization

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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