Synthesis of Triethynylborazine-Polyhydromethylsiloxane Copolymers and its Ceramization

Ji Feng Jiang; Kang Kang Guo; Ya Ping Zhu; Fan Wang; Hui Min Qi

doi:10.4028/www.scientific.net/AMR.774-776.629

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 774-776Synthesis of...

Synthesis of Triethynylborazine-Polyhydromethylsiloxane Copolymers and its Ceramization

Abstract:

Triethynylborazine-polyhydromethylsiloxane copolymers (TEB-PHMSs) were prepared through hydrosilylation reaction between -C≡CH attached to boron and ≡Si-H. The structures of TEB-PHMSs were characterized by Fourier transform Infrared (FT-IR) and Nuclear Magnetic Resonance (NMR) spectroscopy. Their cure behavior were examined by Differential Scanning Calorimeter (DSC) and FT-IR, and then thermostability and ceramization of cured TEB-PHMS were investigated by Thermogravimetric analysis (TGA), pyrolysis-GC-MS, X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM). The results indicated that TEB-PHMSs could be cured and converted into an outstanding thermostable SiBCN ceramics.

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Periodical:

Advanced Materials Research (Volumes 774-776)

Pages:

629-633

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.774-776.629

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Online since:

September 2013

Authors:

Ji Feng Jiang, Kang Kang Guo, Ya Ping Zhu, Fan Wang, Hui Min Qi

Keywords:

Hydrosilylation, Precursor, Triethynylborazine

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