Enhancement of Electrical Properties of ZnO: Al Thin Films on Transparent TPT Substrates by SiO2 Buffer Layers

Article Preview

Abstract:

The electrical properties need to be improved, although Aluminum doped ZnO thin films (ZnO: Al) have been successfully deposited on transparent TPT substrates by our group. In this paper, ZnO: Al film was deposited on TPT substrate with SiO2 buffer layer by RF magnetron sputtering. The obtained film had a hexagonal structure and highly (002) preferred orientation. Compared with ZAO film without buffer layer, the lattice constant distortion of the film with buffer layer was decreased and the compressive stress was decreased by 9.2%, reaching to 0.779GPa. The carrier concentration and hall mobility of the film with buffer layer were both increased; especially the carrier concentration was enhanced by two orders of magnitude, reaching to 2.65×10+20/cm3. The resistivity of ZAO film with SiO2 buffer layer was about 7.6×10-3 Ω·cm and the average transmittance was over 70% in the range of 450~900nm.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 774-776)

Pages:

954-959

Citation:

Online since:

September 2013

Authors:

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] D.Y. Song, A.G. Aberle, J. Xia, Optimisation of ZnO: Al films by change of sputter gas pressure for solar cell application. Appl. Surf. Sci. 195(2002), p.291.

DOI: 10.1016/s0169-4332(02)00611-6

Google Scholar

[2] C. Oliveira, L. Rebouta, T .D. Lacerda-Arôso, S. Lanceros-Mendez , T. Viseu, C. J. Tavares, J. Tovar, S. Ferdov, E. Alves, Structural and electrical properties of Al doped ZnO thin films deposited at room temperature on poly(vinilidene fluoride) substrates. Thin Solid Films 517(2009).

DOI: 10.1016/j.tsf.2009.02.069

Google Scholar

[3] T.L. Yang, D.H. Zhang, J. Ma, H.L. Ma, Y . Chen, Transparent conducting ZnO: Al films deposited on organic substrates deposited by r. f. magnetron-sputtering. Thin Solid Films 326(1998) , p.60.

DOI: 10.1016/s0040-6090(98)00763-9

Google Scholar

[4] Y. S. Jung, H.W. Choi , K.H. Kim , S.J. Park , H.H. Yoon , Properties of AZO Thin Films for Solar Cells Deposited on Polycarbonate Substrates. Journal of the Korean Physical Society  55(2009), p. (1945).

DOI: 10.3938/jkps.55.1945

Google Scholar

[5] K.I. Lee, E.K. Kim, H.D. Kim, H.I. Kang, J.T. Song, Low temperature Al doped ZnO films on a flexible substrate by DC sputtering. Phys. stat. sol. 10(2008), p.3344.

DOI: 10.1002/pssc.200778895

Google Scholar

[6] S. Fernandez, F.B. Naranjo, Optimization of aluminum-doped zinc oxide films deposited at low temperature by radio-frequency sputtering on flexible substrates for solar cell applications. Sol. Energy Mater. Sol. Cells 94(2010), p.157.

DOI: 10.1016/j.solmat.2009.08.012

Google Scholar

[7] Y.D. Liu, Q. Li, H.L. Shao, Properties of ZnO: Al films deposited on polycarbonate substrate. Vacuum 83(2009), p.1435.

DOI: 10.1016/j.vacuum.2009.05.006

Google Scholar

[8] X.T. Hao, J. Ma, D.H. Zhang, Y.G. Yang, H.L. Ma , C.F. Cheng, X.D. Liu, Comparison of the properties for ZnO: Al films deposited on polyimide and glass substrates. Mater. Sci. Eng., B 90(2002), p.50.

DOI: 10.1016/s0921-5107(01)00828-5

Google Scholar

[9] H.L. Ma, X.T. Hao, J. Ma, Y.G. Yang, S.L. Huang, F. Chen, Q.P. Wang, D.H. Zhang, Bias voltage dependence of properties for ZnO: Al films deposited on flexible substrate. Surf. Coat. Technol. 161(2002) , p.58.

DOI: 10.1016/s0257-8972(02)00396-1

Google Scholar

[10] Y.Y. Liu, Y.Z. Yuan, C.F. Li, X.U. Gao, X.Z. Cao, J.B. Li, The structure and photoluminescence properties of RF-sputtered films of ZnO on Teflon substrate. Mater. Lett. 62 (2008), p.2907.

DOI: 10.1016/j.matlet.2008.01.070

Google Scholar

[11] Y.C. Lin, M.Z. Chen, C.C. Kuo, W. T. Yen, Electrical and optical properties of ZnO: Al film prepared on polyethersulfone substrate by RF magnetron sputtering . Colloids and Surfaces A: Physicochem. Eng. Aspects 337(2009), p.52.

DOI: 10.1016/j.colsurfa.2008.11.049

Google Scholar

[12] S. Fernández, A. Martínez-Steele, J.J. Gandía, F.B. Naranjo, Radio frequency sputter deposition of high-quality conductive and transparent ZnO: Al films on polymer substrates for thin film solar cells applications. Thin Solid Films 517(2009).

DOI: 10.1016/j.tsf.2008.11.097

Google Scholar

[13] W.F. Liu, G.T. Du, Y.F. Sun, J.M. Bian, Y. Cheng, T.P. Yang, Y.C. Chang, Y.B. Xu, Effects of hydrogen flux on the properties of Al-doped ZnO films sputtered in Ar + H2 ambient at low temperature. Appl. Surf. Sci. 253 (2007), p.2999.

DOI: 10.1016/j.apsusc.2006.06.049

Google Scholar

[14] R.J. Hong, J.D. Shao, H.B. He, Z.X. Fan, Influence of buffer layer thickness on the structure and optical properties of ZnO thin films. Appl. Surf. Sci. 252(2006), p.2888.

DOI: 10.1016/j.apsusc.2005.04.041

Google Scholar

[15] J. Lee, D.J. Lee, D.G. Lim, K. Yang, Structural, electrical and optical properties of ZnO: Al films deposited on flexible organic substrates for solar cell applications. Thin Solid Films 515(2007), p.6094.

DOI: 10.1016/j.tsf.2006.12.099

Google Scholar

[16] M.A. Martfnez, J. Herrero, M.T. Gutierrez, Deposition of transparent and conductive Al-doped ZnO thin films for photovoltaic solar cells. Sol. Energy Mater. Sol. Cells 45(1997), p.75.

DOI: 10.1016/s0927-0248(96)00066-9

Google Scholar

[17] C.M. Lee, A. Park, Y.J. Cho, M. Park, W.I. Lee, H.W. Kim, Influence of ZnO buffer layer thickness on the electrical and optical properties of indium zinc oxide thin films deposited on PET substrates. Ceram. Int. 34(2008), p.1093.

DOI: 10.1016/j.ceramint.2007.09.083

Google Scholar

[18] X.X. Liu, Z.G. Jin , S.J. Bu, J . Zhao, Z.F. Liu, Effect of buffer layer on solution deposited ZnO films. Mater. Lett. 59(2005), p.3994.

DOI: 10.1016/j.matlet.2005.07.052

Google Scholar

[19] C.Y. Hsu, T.F. Ko, Y.M. Huang, Influence of ZnO buffer layer on AZO film properties by radio frequency magnetron sputtering. J. Eur. Ceram. Soc. 28(2008), p.3065.

DOI: 10.1016/j.jeurceramsoc.2008.05.008

Google Scholar

[20] Z.L. Pei, X.B. Zhang, G.P. Zhang, J. Gong, C. Sun, R. F. Huang, L. S. Wen, Transparent conductive ZnO: Al thin films deposited on flexible substrates prepared by direct current magnetron sputtering. Thin Solid Films 497(2006), p.20.

DOI: 10.1016/j.tsf.2005.09.110

Google Scholar

[21] M. Fujita, N. Kawamoto, M. Sasajima, Y. J Horikoshi, Molecular beam epitaxy growth of ZnO using initial Zn layer and MgO buffer layer on Si(111) substrates.J. Vac. Sci. Technol. B 22(2004), p.1484.

DOI: 10.1116/1.1740766

Google Scholar

[22] D. A . Byung , G. K. Young, H. O. Sang, J. H . Song, H. J. Kim, buffer layer on the electrical properties of GZO film deposited on PET substrate. Thin Solid Films 517(2009), p.6414.

DOI: 10.1016/j.tsf.2009.02.057

Google Scholar

[23] X. J. Wang, Q. S. Lei, W. Xu, W. L. Zhou, Yu J, Preparation of ZnO: Al thin film on transparent TPT substrate at room temperature by RF magnetron sputtering technique Mater. Lett. 63(2009), p.1371.

DOI: 10.1016/j.matlet.2008.12.027

Google Scholar

[24] L .P. Peng, L . Fang, X. F. Yang, Y. J. Li, Q. L. Huang, F. Wu, C Y. J. Kong, Effect of annealing temperature on the structure and optical properties of In-doped ZnO thin films .J. Alloys Compd 484(2009), p.575.

DOI: 10.1016/j.jallcom.2009.04.139

Google Scholar

[25] Z. C. Jin, I.J. Hamberg, C.G. Granqvist, Optical properties of sputter-deposited ZnO: Al thin films.J. Appl. Phys. 64(1988), p.5117.

DOI: 10.1063/1.342419

Google Scholar

[26] B.Y. Oh, M. C.J. Jeong, W. Lee, J.M. Myoung, Properties of transparent conductive ZnO: Al films prepared by co-sputtering . Cryst. Growth 274(2005, p.453.

DOI: 10.1016/j.jcrysgro.2004.10.026

Google Scholar

[27] H.C. Ong, A.X.E. Zhu, G.T. Du, Dependence of the excitonic transition energies and mosaicity on residual strain in ZnO thin films. Appl. Phys. Lett. 80(2002), p.941.

DOI: 10.1063/1.1448660

Google Scholar

[28] R. Cebulla, R. Wendt, K. J. Ellmer, Al-doped zinc oxide films deposited by simultaneous rf and dc excitation of a magnetron plasma: Relationships between plasma parameters and structural and electrical film properties. J. Appl. Phys. 83(1998).

DOI: 10.1063/1.366798

Google Scholar

[29] H.P. He, F. Zhuge, Z.Z. Ye, L.P. Zhu, B.H. Zhao, J.Y. Huang, Strain and its effect on optical properties of Al-N codoped ZnO films.J. Appl. Phys. 99 (2006)023503–023507.

DOI: 10.1063/1.2161419

Google Scholar

[30] G. Fang, D. Li, B. Yao, Fabrication and characterization of transparent conductive ZnO: Al thin films prepared by direct current magnetron sputtering with highly conductive ZnO(ZnAl2O4) ceramic target. J. Cryst. Growth 247(2003), p.393.

DOI: 10.1016/s0022-0248(02)02012-2

Google Scholar