Hydrogen-Rich Gas Formation Characteristics under Microwave Catalytic Pyrolysis of Sewage Sludge

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Microwave catalytic pyrolysis of sewage sludge were conducted on a single mode microwave reactor. The effects of CaO and steam on hydrogen-rich gas formation characteristics were analyzed. The results indicated that the CaO can improve the formation of H2 and CO. When CaO in sewage sludge increased from 0 to 0.75 g/(g dried sludge), the H2 and CO concentration increased from 62 vol.% to 77 vol.%, while CH4 and CO2 concentrations decreased from 28 vol.% to 9 vol.%. The steam can also improve the formation of H2 and CO, with 1.59 g/min of the steam flowrate, the H2 and CO concentration increased to the maximum of 81 vol.%, and the CH4 and CO2 concentration decreased to the minimum of 16 vol.%. When the steam gasification was coupled with the CaO catalyzing, the H2 concentration can reach to 61 vol.%, which was 79.3% higher than the experimental conditions absent of steam and CaO.

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Advanced Materials Research (Volumes 781-784)

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2429-2432

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September 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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