Study on Bio-Fuels Drop Acid by [BSPy]HSO4 Catalytic Esterification

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Abstract:

Research on the synthesis of BrOnsted acidic ionic liquid by the method of solvent, the pyrolysis bio-fuel with cornus wisoniana oil drop acid esterification reaction, the catalyst dosage, reaction time and reaction temperature on the effects of the acid dropping and in the best optimization under the condition of the stability of the catalyst were investigated. The experimental results show that [BSPHSO4 with high catalytic activity, optimization of process conditions as follows: 1.2% of catalyst, reaction temperature 75 °C, reaction time of 70 min, acid value reduced to 2.0 mg KOH/g. By optimizing the cycle experiment, the stability of the catalyst performance is good, the catalytic activity is relatively stable.

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Advanced Materials Research (Volumes 781-784)

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2433-2437

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September 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] Changzhu Li, Liangbo Zhang, Perwang Li. Selection breeding of oil tree clones of Swida wilsoniana[J]. Journal of Central South University of Forestry & Technology, 2010, 30(7): 1-8.

Google Scholar

[2] Li Li, Changzhu Li, Peiwang Li. Precocity and high-yield experiment of 15 Swida wilsoniana clones [J]. Hunan Forestry Science & Technology, 2008, 35(6): 34-37.

Google Scholar

[3] Changzhu Li, Peiwang Li, Zhihong Xiao. Current progress in research and development of woody biodiesel oil feedstock and its industrialization prospect in China[J]. Journal of China Agricultural University, 2012, 17(6): 165-170.

Google Scholar

[4] Cole A C, Jensen J L, Ntai L, et al. Novel BrÖnsted Acidic Ionic Liquids and Their Use as Dual Solvent-Catalysts. J Am Chem Soc, 2002, 124(21): 5 962-5 963.

DOI: 10.1021/ja026290w

Google Scholar

[5] Changzhu Li, Aihua Zhang, Zhihong Xiao. Preparation of bio-diesel from Cornus wilsoniana fruit oil with basic ionic liquids as catalyst[J]. Journal of Central South University of Forestry & Technology, 2011, 3(31): 38-43.

Google Scholar

[6] Si Chen, Liying Yu, Jian Zhang. Optimization of the synthesis of 1-(4-sulfonic acid) butyl-pyridinium hydrosulfate ionic liquid[J]. Journal of Jilin Institute of Chemical Technology, 2011, 28(11): 39-41.

Google Scholar

[7] Qin Wu, Binqi Dong, Minghan Han. Synthesis and Characterization of Novel BrФnsted Acidic Ionic Liquids[J]. Spectroscopy and Spectral Analysis, 2007, 27(10): 2027-(2031).

Google Scholar