Characterization and Photocatalytic Activity of Composite La-TiO2/ITO Thin-Film Electrodes

Article Preview

Abstract:

The different molar ratios of La/Ti (0.025, 0.050, 0.075 and 0.100) photocatalytic electrodes use in this study were synthesized by sol-gel method and dip-coating method. The XRD pattern of TiO2/ITO presents only anatase phases, [1] but for La-TiO2/ITO presents both anatase and rutile phases. The SEM image of the La-TiO2/ITO showed particles of regular shapes with smaller size (<10nm) compared to the TiO2/ITO, which presented uniform particles of spherical structure and larger size (20nm).The La-TiO2/ITO photocatalytic electrode with molar ratio 0.050 shows the best ability both on the absorbtion and photocatalytsis. Applied potential 2.0V would effectively increase the photoelectrocatlaytic activity under visible light irradiation.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 79-82)

Pages:

899-902

Citation:

Online since:

August 2009

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2009 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] He, C., Li, X. Z., Graham, N., and Wang, Y. Preparation of TiO2/ITO and TiO2/Ti photoelectrodes by magnetron sputtering for photocatalytic application., Applied Catalysis A : General, 305, 54-63. (2006).

DOI: 10.1016/j.apcata.2006.02.051

Google Scholar

[2] Wu, J. C. S. and Chen, C. H. A visible-light response Vanadium-doped titania nanocatalyst by sol-gel method., Journal of Photochemistry and Photobiology A: Chemistry, 163(3), 509-515. (2004).

DOI: 10.1016/j.jphotochem.2004.02.007

Google Scholar

[3] Wang, J., Uma, S. and Klabunde, K. J. Visible light photocatalysis in transition metal incorporated titania-silica aerogels., Applied Catalysis B: Environmental, 48(2), 151-154. (2004).

DOI: 10.1016/j.apcatb.2003.10.006

Google Scholar

[4] Chen, H. W., Ku, Y. and Kuo, Y. L. Effect of Pt/TiO2 characteristics on temporal behavior of o-cresol decomposition by visible light-induced photocatalysis., Water Research, In Press, Corrected Proof. (2007).

DOI: 10.1016/j.watres.2007.02.021

Google Scholar

[5] Daneshvar, N., D. Salari and A. R. Khataee. Photocatalytic Degradation of Azo Dye Acid Red 14 in Water on ZnO as An Alternative Catalyst to TiO2. , Photochemistry and Pohotbiology A: Chemistry, 162, 317-322. (2004).

DOI: 10.1016/s1010-6030(03)00378-2

Google Scholar

[6] Habibi, M. H., and Talebian, N. Photocatalytic degradation of an azo dye X6G in water : A comparative study using nanostructured Indium tin oxide and titanium oxide thin films., Dyes and Pigments, 73, 186-194. (2007).

DOI: 10.1016/j.dyepig.2005.11.006

Google Scholar

[7] Habibi, M. H., Talebian, N., and Choi, J. Characterization and photocatalytic activity of nanostructured indium tin oxide thin-film electrode for azo-dye degradation., Thin Solid Films, 515, 1461-1469. (2006).

DOI: 10.1016/j.tsf.2006.04.037

Google Scholar

[8] Parida K.M., Nruparaj Sahu Visible light induced photocatalytic activity of rare earth titania nanocomposities. , Journal of Mlecular Catalysis A : Chemical, 287, 151-158. (2008).

DOI: 10.1016/j.molcata.2008.02.028

Google Scholar

[9] Muruhanandham, M. and M. Swaminathan. Photocatalytic Decolourisation and Degradation of Reactive Orange 4 by TiO2-UV Process. , Dyes and Pigments, 68, 133-142. (2006).

DOI: 10.1016/j.dyepig.2005.01.004

Google Scholar

[1] 0 TI.

Google Scholar

025LTI.

Google Scholar

075LTI.

Google Scholar

1LTI pH4 pH7 pH10 C/C0.

Google Scholar

[1] 0 TI.

Google Scholar

025LTI.

Google Scholar

075LTI.

Google Scholar

1LTI Fig. 7. color removal rate of adsorption for photocatalytic electrodes at varied pH Fig. 8. color removal rate of photocatalyst for photocatalytic electrodes under UV light at varied pH Time(min) 0 60 120 180 240 C/C0.

Google Scholar

[1] 0 TI.

Google Scholar

025LTI 005LTI.

Google Scholar

075LTI.

Google Scholar

1LTI Time(min) 0 60 120 180 240 C/C0.

Google Scholar

[1] 0 V.

Google Scholar

[2] 0 V.

Google Scholar

[4] 0 V Fig. 9. removal rate of photocatalyst for photocatalytic electrodes under visible light at varied pH Fig. 10. removal rate of photocatalyst for photocatalytic electrodes at varied potential.

Google Scholar