Structure Studies on Order Assemblage of ManganeseII Complexes

Yu  Liu; Shan Shan  Zhang; Jian Gao; Tian Zhu  Yang; Hong Xiao  Tian

doi:10.4028/www.scientific.net/AMR.790.57

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 790Structure Studies on Order Assemblage of...

Structure Studies on Order Assemblage of Manganese^II Complexes

Abstract:

The manganese^IIcomplex [Mn (C₉H₉O₃)₂(H₂O)₂], the Mn^IIatom is located on a twofold axis and is coordinated by two ethylvanillinate anions and two water molecule in a distorted octahedral geometry. The ethylvanillinate ligand chelates to the Mn^II atom through its ethyl and hydroxyl O atoms, with greatly differing Mn-O bond distances (2.3988(15)Å and 2.0675(13)Å).Adjacent complex link to each other via hydrogen bonds forming the three-dimensional supramolecular structure.

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Periodical:

Advanced Materials Research (Volume 790)

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57-60

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.790.57

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Online since:

September 2013

Authors:

Yu Liu, Shan Shan Zhang, Jian Gao, Tian Zhu Yang, Hong Xiao Tian

Keywords:

Electrostatic Interaction, Manganese^IIComplex, Photosystem Ii, Supramolecular Structure

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