Influence of Propylene Carbonate as A Plasticizer in CMC-OA Based Biopolymer Electrolytes: Conductivity and Electrical Study

Article Preview

Abstract:

Carboxyl methylcellulose (CMC) doped with oleic acid (OA) and plasticized with propylene carbonate (PC) was successfully manufactured into thin film using solution cast technique. Impedance study shows the ionic conductivity falls into two region. With the addition of 5wt% of PC the ionic conductivity falls from 2.11x10-5S/cm to 2.00x10-7 S/cm. The highest conductivity gained at ambient temperature is 2.52x10-7 S/cm for sample CMC-OA-PC 10 wt. %. The system obeys the non-Debye dependence based on the dielectric and modulus study.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

184-188

Citation:

Online since:

September 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Ramesh, S. & Arof A.K. Ionic conductivity studies of plasticized poly (vinyl chloride) polymer electrolytes. Materials Science and Engineering B.BB5 (2001)11-15.

DOI: 10.1016/s0921-5107(01)00555-4

Google Scholar

[2] Woo, H.J., Majid S.R., &Arof A.K. 2012. Dielectric properties and morphology of polymer electrolyte based on poly (ε-caprolactone) and ammonium Thiocynate. Materials Chemistry and Physics.134 (2012) 755-761.

DOI: 10.1016/j.matchemphys.2012.03.064

Google Scholar

[3] MD Isa, K.B., Othman, L. & Osman Z. Comparative Studies on plasticized and plasticized polycrylonitrile (PAN) polymer electrolytes containing lithium and sodium salts. Sainsmalaysiana. 40(7) (2011) 691-694.

Google Scholar

[4] Chai, M.N. & Isa, M.I.N. Carboxyl methylcellulose solid polymer electrolytes: Ionic conductivity and dielectric study. Journal of Current Engineering Research. 1(2) (2011) 23-27.

Google Scholar

[5] Kumar, M. & Sekhon, S.S. Role of plasticizer's dielectric constant on conductivity modification of PEO-NH4F polymer electrolyte. European polymer journal. 38 (2001) 1297-1304.

DOI: 10.1016/s0014-3057(01)00310-x

Google Scholar

[6] Yahya, M.Z.A. & Arof, A.K. Effect of oleic acid plasticizer on chitosan- lithium acetate solid polymer electrolytes. European polymer journal. 30 (2003) 897-902.

DOI: 10.1016/s0014-3057(02)00355-5

Google Scholar

[7] Vieira DF, Avellaneda CO, Pawlicka. A Conductivity study of a gelatin-based polymer electrolyte. ElectrochimicaActa. 53(2007) 1404-1408.

DOI: 10.1016/j.electacta.2007.04.034

Google Scholar

[8] Isa, M.D., Othman, L. & Osman, Z. Comparative Studies on plasticized and plasticized polycrylonitrile (PAN) polymer electrolytes containing lithium and sodium salts. Sainsmalaysiana. 40(7) (2011) 691-694.

Google Scholar

[9] Samsudin, A. S. & Isa, M.I.N. Characterization of carboxy methylcellulose doped with DTAB as new types of biopolymer electrolytes. Bull. Mater. Sci. 35 (2012) 1123-1131.

DOI: 10.1007/s12034-012-0396-1

Google Scholar

[10] Sit, Y. K., Samsudin, A. S. & Isa, M.I.N. Ionic Conductivity Study on Hydroxyethyl Cellulose (HEC) doped with NH4Br Based Biopolymer Electrolytes. Research Journal of Recent Sciences.1(11) (2012) 16-21.

Google Scholar