Synthesis, Spectral Properties of Di-(2-methyl-8-hydroxyquinoline)Zinc

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Abstract:

The complex of di-(2-methyl-8-hydroxyquinoline) zinc (Zn (2-mq)2) was synthesized. The complex was characterized by elemental analysis, 1HNMR, 13CNMR, infrared, UV-vis, XRD and molar conductivity. The zinc (II) ion was found to coordinate to the oxygen atom of phenolic hydroxyl and nitrogen atoms of 2-methyl-8-hydroxyquinoline and the complex conformes to 1:2 metal-to-ligand stoichiometry. The fluorescence properties of the complex in solid and solution were studied. The complex exhibits yellow light under the excitation of UV light. The solvent factors influencing the fluorescent intensity are discussed.

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189-192

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October 2013

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] S. S. Djebbar, B. O. Benali, J. P. Deloume: Polyhedron Vol. 16 (19977), p.2175.

Google Scholar

[2] P. Bhattacharyya, J. Parr, A. T. Ross: J. Chem. Soc. Dalton Vol. 40 (1998), p.3149.

Google Scholar

[3] L. He, S. H. Gou, Q. F. Shi: J. Chem. Crystallogr. Vol. 29 (1999), p.207.

Google Scholar

[4] J. C. Wu, N. Tang, W. S. Liu, M. Y. Tan, A. S. C. Chan: Chinese Chem. Lett. Vol. 12 (2001), p.757.

Google Scholar

[5] C. M. Liu, R. G. Xiong, X. Z. You, Y. J. Liu, K. K. Cheung: Polyhedron Vol. 15 (1996), p.4565.

Google Scholar

[6] S. S. Djebbar, B. O. Benali, J. P. Deloume: Transit. Metal. Chem. Vol. 23 (1998), p.443.

Google Scholar

[7] Y. J. Hamada: IEEE Transactions on Electron Devices Vol. 44 (1997), p.1208.

Google Scholar