Crystal Structure of Mg (II) Complex with 1,5-Naphthalenedisulfonate

Wen Hua Zhao; Yuan Tao Chen; Xi Shi Tai

doi:10.4028/www.scientific.net/AMR.830.197

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 830Crystal Structure of Mg (II) Complex with...

Crystal Structure of Mg (II) Complex with 1,5-Naphthalenedisulfonate

Abstract:

A new Mg (II) complex, [Mg (H₂O)₆]·(L) (L=1,5-naphthalenedisulfonate) has been obtained by the reaction of MgCl₂·6H₂O with sodium 1,5-naphthalenedisulfonate in the CH₃CH₂OH/H₂O (V:V=3:1) solution. The complex was characterized by X-ray single crystal diffraction analysis. The results showed that the local geometry around central Mg (II) ion can be described a distorted octahedral environment which connected by six water molecules. The one domensional chained structure of complex formed by hydrogen bonds of intramolecule and intermolecule and π-π stacking.