Crystal Structure of Na(I) Complex with 1,5-Naphthalenedisulfonate

Li Hua Wang; Zhi Xiang Ji

doi:10.4028/www.scientific.net/AMR.830.185

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 830Crystal Structure of Na(I) Complex with...

Crystal Structure of Na(I) Complex with 1,5-Naphthalenedisulfonate

Abstract:

A new Na (I) complex, [Na (H₂O)₅(DMF)]·(L) (L=1,5-naphthalenedisulfonate) has been obtained in the CH₃CH₂OH and a little DMF solution. The complex was characterized by X-ray single crystal diffraction analysis. The results showed that the local geometry around central Na (I) ion can be described a distorted octahedral environment which connected by five water molecules and one DMF molecule. The complex formed one dimensional chain structure through intramolecule and intermolecule hydrogen bonds and π-π stacking.

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Periodical:

Advanced Materials Research (Volume 830)

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185-188

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.830.185

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Online since:

October 2013

Authors:

Li Hua Wang*, Zhi Xiang Ji

Keywords:

1, 5-Naphthalenedisulfonate, Crystal Structure, Na (I) Complex

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References

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