Synthesis and Characterization of Binuclear Ruthenium Vinyl Complexes with Dithienylethene Unit

Abstract:

A novel binuclear ruthenium vinyl complexes with dithienylethene unit II [RuCl (CO)(PMe₃)₃]₂(μ-CH=CH-DTE-CH=CH) has been synthesized and characterized by elemental analysis and NMR spectra. Meanwhile, the crystal of II was obtained and determined by X-ray single-crystal diffraction.

• Periodical: Advanced Materials Research (Volumes 834-836)
• Pages: 259-262
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.834-836.259
• Online since: October 2013
• Authors: Yan Lin, Han Feng Cui, Hao Fan
• Keywords: Characterization, Crystal Structure, Ruthenium Vinyl Complexes, Synthesis

References

[1] Feringa, B. L. Ed. Molecular Switches; Wiley-VCH: Weinheim, (2001).

[2] Irie, M. Chem. Rev. Vol. 100 (2000), 1685.

[3] Irie, M., Fukaminato, T., Sasaki, T., Tamai, N. and Kawai, T. Nature Vol. 420 (2002), 759.

DOI: 10.1038/420759a

[4] H. Tian, S. Yang, Chem. Soc. Rev. Vol. 33 (2004), 85.

[5] Kim, H. J., Jang, J. H., Choi, H., Lee, T., Ko, J., Yoon, M. and Kim, H. -J. Inorg. Chem. Vol. 47 (2008), 2411.

[6] Lee, J. K. -W., Ko, C. -C., Wong, K. M. -C., Zhu, N. and Yam, V. W. -W. Organometallics Vol. 26 (2007), 12.

[7] Roberts, M. N., Nagle, J. K., Finden, J. G., Branda, N. R. and Wolf, M. O. Inorg. Chem. Vol. 48 (2009), 19.

[8] Y. Lin, J. Yuan, M. Hu, J. Cheng, J. Yin, S. Jin and S. H. Liu Organometallics Vol. 28 (2009), 6402.

[9] Y. Lin, C. Jiang, F. Hu, J. Yin, G-A. Yu and S. H. Liu Dyes and Pigments Vol. 99 (2013), 995.

[10] P. Yuan, X. -H. Wu, G. Yu, D. Du and S. H. Liu, J. Orgnomet. Chem. Vol. 692 (2007), 3588.

[11] Yamada, T., Kobatake, S., Muto, K. and Irie, M. J. Am. Chem. Soc. Vol. 122 (2000), 1589.

[12] Kobatake, S., Irie, M. Bull. Chem. Soc. Jpn. Vol. 77 (2004), 195.