Synthesis and Characterization of P (AAEA-Co-Aa)-PVP-PEG/Gold Nanoparticle Composite Hydrogel with Pore and Semi-Interpenetration Structure

Abstract:

A semi-interpenetrating network hydrogel with pore structure (P-S-IPN) was prepared by solution polymerization with 4-acetyl acryloyl ethyl acetate (AAEA) and crylic acid (AA) as monomers, polyvinylpyrrolidone (PVP) as the second network and polyving akohol 2000(PEG2000) as a pore-foaming agent. Gold nanoparticle composite hydrogel (GNPs gel) was obtained through in-situ reduction reaction by using P-S-IPN as a template. P-S-IPN exhibits excellent mechanical strength, the maximum compressive strength is 14.0 Mpa. The influence of the dosage of PEG2000 on the swelling/deswelling properties of P-S-IPN and GNPs gel was investigated. The pore structures could shorten the time that P-S-IPN takes to reach swelling equilibrium from 170min to 75min, improve the ability of P-S-IPN to absorb AuCl₄^-. The swelling/deswelling properties of GNPs gel under an applied voltage showed when the concentration of NaCl solutions exceed 0.025mol/L, the hydrogel swells, when the concentration of NaCl solutions is below 0.025mol/L, it deswells.

• Periodical: Advanced Materials Research (Volumes 834-836)
• Pages: 90-95
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.834-836.90
• Online since: October 2013
• Authors: Kun Lu Li, Song Bai Lin*, Ru Pan Chen, Yun Long Li, Da Gang Li
• Keywords: AAEA, Gold Nanoparticle, Hydrogels, Porosint

References

[1] L. Wouler; D.P. Filip: Macromol. Symp, 2004, 210(1): 483-491.

[2] K. Haraguchi, T. Takehisa, S. Fan: Macromolecules, 2002, 35 (27): 10162-10171.

[3] K. Haraguchi, T. Takada: Macromolecules ChemPhys, 2005, 206(15): 1530-1540.

[4] P. Ghosh, Gang Han, M. De, etal: Advanced drug delivery reviews. 2008, 60(11): 1307-1315.

[5] B. Merchant: Biologicals. 1998, 26(1): 49-59.

[6] A.C. Gluhoi, S. Lin, B.E. Dnieuwenhuys: Catalysis Today. 2004, 90(3-4): 175-181.

[7] V. Ramtenki, V.D. Anumon, M.V. Badiger, etal: Colloids and Surfaces A-physicochemical and Engineering Aspects. 2012, 414: 296-301.

DOI: 10.1016/j.colsurfa.2012.08.026

[8] Zhenke Zhu, Rong Tan, Wenqing Sun, etal: Journal of Catalysis. 2011, 32(9): 1508-1512, in chinese.

[9] S.Y. Kim, H.S. Shin, Y.M. Lee, etal: Journal of Applied Polymer Science. 1999, 73(9): 1675–1683.

[10] Songbai Lin, Conghui Yuan, Airu Ke, etal: Acta Chimca Sinica, 2010, 68(8): 89-826, in chinese.

[11] I. Olivine, T. Tanaka: The Journal of Chemical Physics, 1982, 77: 5725-5729.

[12] P.J. Flory: Principles of Polymer Chemistry [M]. 15th ed. Ithaca: Cornell University Press, 1992: 586.