Synthesis and Characterization of Novel Hybrid Ladderlike Polysilsesquioxanes Containing Polypropylene Moieties

Deock Sam Park; Tae Sung Ha; Jung Hyurk Lim; Kyung Min Kim

doi:10.4028/www.scientific.net/AMR.845.204

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 845Synthesis and Characterization of Novel Hybrid...

Synthesis and Characterization of Novel Hybrid Ladderlike Polysilsesquioxanes Containing Polypropylene Moieties

Abstract:

Novel ladderlike polysilsesquioxanes containing polypropylene moieties (LPS-PP) were synthesized from LPS having chloromethylphenyl groups (LPS) and polypropylene having hydroxyl groups (PP-OH). LPS-PP was characterized by FT-IR, DSC, SEM, EDX, and TGA. The obtained LPS-PP shows no melting temperature due to the disappearance of melting temperature of PP, indicating the rigidity of Si-O-Si backbone in ladderlike LPS. The char yield of LPS-PP is higher than that of PP-OH because of the silica parts of LPS. This new LPS-PP can be an interesting candidate to fabricate hybrid materials using interactions or compatibility between PP moieties of LPS and various organic polymers.

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Periodical:

Advanced Materials Research (Volume 845)

Pages:

204-208

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.845.204

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Online since:

December 2013

Authors:

Deock Sam Park, Tae Sung Ha, Jung Hyurk Lim, Kyung Min Kim*

Keywords:

Hybrid Material, Ladderlike Polysilsesquioxanes, Polypropylene (PP), Silsesquioxanes

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* - Corresponding Author

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