Preparation of Straw Superabsorbent Composite Material by Microwave Method

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Abstract:

By microwave method, a superabsorbent function composite material was prepared by grafting sodium acrylate onto straw flour using potassium persalfate (K2S2O8) and N, N'-methylene bis acrylamide as an initiator and crosslinker, respectively. The effect of various preparation conditions on its water absorbency was investigated. When the straw flour content was 6%, the acrylic acid content was 20.0g, the amount of initiator was 0.4%, the neutralization degree of monomer was 80%, the reaction temperature was 70°C and the amount of crosslinker was 0.05%, the materials absorbency was 1360 times in distilled water and 152 times in 0.9% salt-water at ambient temperature. It had also high water retention. The analyses of SEM indicate that sodium acrylate is grafted on the polysaccharides of straw flour.

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337-343

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December 2013

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] Xinxi Zou. Superabsorbent [M]. Chemical Industry Publishing Company, (2002).

Google Scholar

[2] JIANG Fatang, LI Wanfen. Preparation and Charcterization of Konjac Superabsorbent Polymer. Journal of Wuhan University of Technology - Mater. Sci. Ed. 2006, 26(4): 87-91.

DOI: 10.1007/bf02841212

Google Scholar

[3] Mehem Celik, Mehmet Sacak. Synthesis and Characterization of Starch-poly (methyl methacrylate) Graft Copolymers [J]. J. Appl. Polym. Sci., 2002, 86: 53-57.

DOI: 10.1002/app.10902

Google Scholar

[4] Mingzhu Liu, Shufu Peng. A Novel Method to Prepare Superabsorbent Polymers[J]. Journal of Lanzhou University ( Natural Sciences ) 2002, 38 (3) : 63-67.

Google Scholar

[5] Shin Kuwabara, Hitoshi Kubota. Water-absorbing Character- istics of Acrylic Acid-grafted Carboxymethyl Cellulose Synthe- sized by Photografting [J]. J. Appl. Pol3m. Sci., 1996, 60: 1965-(1970).

DOI: 10.1002/(sici)1097-4628(19960613)60:11<1965::aid-app20>3.0.co;2-z

Google Scholar

[6] Song Liu, Lei Li. The Development on Synthesis of Superab- sorbents [J], Polymer Materials Science and Engineering, 2001, 17(3): 11-14.

Google Scholar

[7] Wenfu Lee, Yulin Huang. Superabsorbent Polymeric Materials IX: Effect of Cationic Structure on Swelling Behavior of Crosslinked Poly (sodium acrylate-co-cationic monomers) in Aqueous Salt Solutions[J]. J. Appl. Polym. Sci. , 2001, 81: 1827-1837.

DOI: 10.1002/app.1616

Google Scholar

[8] Zhu zhi-feng, Zhou Yong-yuan, Zhangweng. Super Absorbents and Its Prospective ApplicationinTextile Industry [J]. Journal of China Textile University, 1994, 20(4): 80-86.

Google Scholar

[9] Jihuai Wu, Jianming Lin, Guoping Li, et all. Influence of the COOH and COONa Groups and Cr osslink Density of Poly (acrylic acid)/Montmorillonite Supembsorbent Composite on Water Absorbency [J]. Polym. Int. , 2001, 50: 1050-1053.

DOI: 10.1002/pi.728

Google Scholar

[10] Kourosh Kabiri, M J Zohuriaan Mehr. Superabsorbent Hydrogel Composites [J]. Polym. Adv. Technol. 2003, 14: 438- 444.

DOI: 10.1002/pat.356

Google Scholar

[11] Wenfu LEE, Paoh Yeh. Superabsorbent Polymeric Materials []. Effect of Initial Total Monomer Concentration on the Swelling Behavior of Crosslinked Poly (sodium acrylate) in Aqueous Salt Solution [J]. J. Appl. Polym. Sci., 1997, 64: 2371-2380.

DOI: 10.1002/(sici)1097-4628(19970620)64:12<2371::aid-app12>3.0.co;2-4

Google Scholar

[12] SUN Zi shun, ,WAN Tao,XIONG Lei. Preparation and Properties of Corn Stalk - composite Superabsorbent. Guangzhou Chemical Industry. 2012, 40(8): 74-77.

Google Scholar

[13] Tan Fengzhi ,Cao Yafeng ,Li Yuan .Preparation of superabsorbent resin from corn straw[J].Journal of Dalian Polytechnic University , 2009,28: 362.

Google Scholar

[14] Williams D H, Fleming I. Spectroscopic Methods on Organic Chemistry [M]. McGraw-Hill Book Company: London, 1980, 3rd ed.

Google Scholar

[15] Maeda, M. Shimahara H. Sugiyamsa, N. Detailed Examination of Branched Structure of Straw Glucomannan [J]. Agr/c. Biol. Chem., 1980, 44: 245-252.

DOI: 10.1080/00021369.1980.10863939

Google Scholar