Effect of Process on the Dielectric Properties of BaTiO3-Based X9R Ceramics

Article Preview

Abstract:

The effect of milling time and sintering process on the dielectric properties of BaTiO3-based X9R ceramics was investigated. The characterization of the raw powders and the sintered ceramic was carried out by X-ray diffraction and scanning electron microscopy. The particle size distribution of the mixed powders was examined by Laser Particle Size Analyzer. The results shown that with the milling time extended, the Cruie Peak was depressed, or even disappeared. Moreover, with the rise of sintering temperature, the dielectric constant of the ceramics increased and the dielectric loss decreased gradually. Eventually, by milling for 11h and sintering at 1090°Cfor 2h, good dielectric properties were obtained, which were ε25°C≥ 2526, εr/εr25°C≤± 12% (–55~200°C), tanδ≤1.12% (25°C).

You might also be interested in these eBooks

Info:

Periodical:

Pages:

18-24

Citation:

Online since:

April 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] D. F. K. Hennings and B. S. Schreinemacher, Temperature-Stable Dielectric Materials in the System BaTiO3-Nb2O5-Co3O4 , J. Eur. Ceram. Soc., 14, 463–71(1994).

DOI: 10.1016/0955-2219(94)90085-x

Google Scholar

[2] H. Chazono. J. Am. Ceram. Soc. 83(2000)101.

Google Scholar

[3] Michael A. Mccoy, William E. Lee, Robin W. Grimes, Analysis of Planar Defects in Nb2O5 -and Bi2O3-doped BaTiO3 Ceramics, J . Mater. Sci. 33 (1998) 5759–5771.

Google Scholar

[4] S. shirasaki, Bull. Chem. Soc. Japan 47(2009)568.

Google Scholar

[5] B.P. Das, Ceram. Trans. 103(2004)261.

Google Scholar

[6] Chu, M. S. H., Hodgkins, C. E. and Dean, T. C. Dielectric ceramic composition with high dielectric constant and flat TC characteristics. US Patent 4, 882, 305, 21 November (1989).

Google Scholar

[7] Hirokazu Chazono, Hiroshi Kishi, Sintering Characteristics in the BaTiO3-Nb2O5-Co3O4 Ternary System: II, Stability of So-called Core–Shell, Structure. J. Am. Ceram. Soc., 83.

DOI: 10.1111/j.1151-2916.1999.tb02143.x

Google Scholar

[1] 101–106 (2000).

Google Scholar

[8] B. Wong and J. A. Pask. Models for Kinetics of Solid State Sintering. J. Am. Ceram. Soc., 1979, 62, 138-144.

Google Scholar

[9] C-H. Kim et al. Effects of milling condition on the formation of core-shell structure in BaTiO3 grains Journal of the European Ceramic Society 28 (2008) 2589–2596.

DOI: 10.1016/j.jeurceramsoc.2008.03.030

Google Scholar

[10] Chu, M. S. H., Hodgkins, C. E. and Dean, T. C., Dielectric ceramic composition with high dielectric constant and flat TC characteristics. US Patent 4, 882, 305, 21 November (1989).

Google Scholar

[11] Hirokazu Chazono, Hiroshi Kishi, Sintering Characteristics in the BaTiO3-Nb2O5-Co3O4 Ternary System: II, Stability of So-called Core–Shell, Structure, J. Am. Ceram. Soc., 83.

DOI: 10.1111/j.1151-2916.1999.tb02143.x

Google Scholar

[1] 101–106 (2000).

Google Scholar

[12] H. Kobayashi, et al, Dielectric ceramic composition and electronic device. (TDK Corporation (Tokyo JP), United states Patent 2002).

Google Scholar