Simulation of Hydrodynamics and Reaction Behavior in an Industrial RFCC Riser

Article Preview

Abstract:

A 2D axi-symmetric, steady state and pressure-based model for the riser of an industrial RFCC unit was developed with ANSYS FLUENT in workbench 13.0. The EulerianEulerian approach was applied to simulate the flow behavior of the two phases and the catalytic cracking reactions. The k-ε gassolid turbulent flow per phase model was used, and the particle-level fluctuations are modeled in the framework of the kinetic theory of granular flow. Two different drag models were used separately to simulate the gas solid interaction in the riser fluidized bed. The 14-lump kinetic model was chosen to describe the complex catalytic cracking of the heavy residual feed stock. The particle volume fraction, velocity and temperature profiles, as well as product yields in the riser were analyzed and validated with results from open literature and the industrial RFCC plant data.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

267-282

Citation:

Online since:

June 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] R. A. Meyers, D. A. Hunt, Handbook of Petroleum Refining Processes, McGraw-Hill, (2003).

Google Scholar

[2] A. K. Das, E. Baudrez, G. B. Marin, and G. J. Heynderickx, Three-Dimensional Simulation of a Fluid Catalytic Cracking Riser Reactor, Ind. Eng. Chem. Res., 2003, 42 (12), 2602-2617• DOI: 10. 1021/ie020744g • Publication Date (Web): 22 April (2003).

DOI: 10.1021/ie020744g

Google Scholar

[3] F. Hernandez-Jimeneza, J.R. Thirdb, A. Acosta-Iborraa, C.R. Mullerb Critical evaluation of Euler-Euler AND Euler-Lagranian modeling strategies in a 2-D gas fluidized bed, conference paper : CFB 10, May 1st through 5th, 2011, Sunriver, Oregon, USA, section 11-2.

Google Scholar

[4] K.N. Theologos, N.C. Markatos, Advanced modeling of fluid catalytic cracking riser-type reactors, A.I. Ch.E. Journal 39, 1993, p.1007–1017.

DOI: 10.1002/aic.690390610

Google Scholar

[5] Y. Zheng, X. Wan, Z. Qian, F. Wei, Y. Jin, Numerical simulation of the gas-particle turbulent flow in riser reactor based on k-e-kp-ep-Q two-fluid model, Chemical Engineering Science, 56, 2001, p.6813 – 6822.

DOI: 10.1016/s0009-2509(01)00319-0

Google Scholar

[6] X. Lan, C. Xu, G. Wang, L. Wu, J. Gao, CFD modeling of gas-solid flow and cracking reaction in two-stage riser FCC reactors, Chemical Engineering Science 64 (2009) 3847 – 3858.

DOI: 10.1016/j.ces.2009.05.019

Google Scholar

[7] S. Vaishali, S. Roy, P. L. Mills, Hydrodynamic simulation of gas–solids downflow reactors, Chemical Engineering Science, 63, 2008, pp.5107-5119.

DOI: 10.1016/j.ces.2008.06.014

Google Scholar

[8] D. Gidaspow, Multiphase Flow and Fluidization: Continuum and Kinetic Theory Description, Academic Press, New York, (1994).

Google Scholar

[9] H. Arastoopour, P. Pakdel, M. Adewumi, Hydrodynamic analysis of dilute gas–solids flow in a vertical pipe, Powder Technol. 62, 1990, p.163–170.

DOI: 10.1016/0032-5910(90)80080-i

Google Scholar

[10] M. Syamlal, T. O, Brien, Derivation of a drag coefficient from velocity–voidage correlation, U.S. Dept. of Energy, Office of Fossil Energy, National Energy Technology Laboratory, Morgantown, West Virginia, April, (1987).

Google Scholar

[11] A. Almuttahar, F. Taghipour, Computational fluid dynamics of high density circulating fluidized bed riser: Study of modeling parameters, Powder Technology 185, 2008, p.11–23.

DOI: 10.1016/j.powtec.2007.09.010

Google Scholar

[12] Matsen, J.M., Mechanisms of choking and entrainment, Powder Technology, 32, 1982, p.22–33.

DOI: 10.1016/0032-5910(82)85003-1

Google Scholar

[13] Peng Li, X. Lan, C. Xu, G. Wang, C. Lu, J. Gao, Drag models for simulating gas–solid flow in the turbulent fluidization of FCC particles, Particuology, 7 , 2009, p.269–277.

DOI: 10.1016/j.partic.2009.03.010

Google Scholar

[14] K. N. Theologos, A. I. Lygeros, N. C. Markatos, Feedstock Atomization Effects on FCC Riser Reactions Selectivity, Chem. Eng. Sci. 1999, 54, 5617.

DOI: 10.1016/s0009-2509(99)00294-8

Google Scholar

[15] T. A. Berry, T. R. McKeen, T. S. Pugsley, and A. K. Dalai, Two-Dimensional Reaction Engineering Model of the Riser Section of a Fluid Catalytic Cracking Unit, Ind. Eng. Chem. Res., 2004, 43 (18), pp.5571-5581• DOI: 10. 1021/ie0306877 • Publication Date (Web): 21 April (2004).

DOI: 10.1021/ie0306877

Google Scholar

[16] A. Gupta, D. Subbarao, Model for the performance of fluid catalytic cracking (FCC) riser reactor: Effect of feed atomization, Chemical Engineering Science, 56(2001), 4489–4503.

DOI: 10.1016/s0009-2509(01)00122-1

Google Scholar

[17] A. Gupta, D. Subbarao, Effect of feed atomization on FCC performance: simulation of entire unit, Chemical Engineering Science, 58(2003), p.4567–4579.

DOI: 10.1016/s0009-2509(03)00341-5

Google Scholar

[18] J. A. Souzaa, J. V. C. Vargasa, O. F. Von Meiena, and W. Martignonib, Numerical simulation of FCC risers, Engenharia Térmica, n‏؛ 4, 2003, pp.17-21.

Google Scholar

[19] R. K. Gupta, V. Kumara, V.K. Srivastavab, Anew generic approach for the modeling of fluid catalytic cracking (FCC) riser reactor, Chemical Engineering Science 62 , 2007, p.4510 – 4528.

DOI: 10.1016/j.ces.2007.05.009

Google Scholar

[20] R. Bader, J. Findlay, T.M. Knowlton, Gas/solids flow patterns in a 30. 5cm diameter circulating fluidized bed, In: Basu, P., Large, J.F. (Eds. ), Circulating Fluidized Bed Technology 2. Pergamon Press, Oxford, UK, 1988, p.123–137.

DOI: 10.1016/b978-0-08-036225-0.50016-2

Google Scholar

[21] International Conference on Circulating Fluidized Beds and Fluidization Technology , CFB 10, May 1st through 5th, 2011, Sunriver Resort, Sunriver, Oregon, USA.

Google Scholar