Synthesis of Core @ Shell Composite Particles with a Tunable Shell Containing Natural Urushiol

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The core @ shell composite particles of polystyrene @ urushiol-titanium chelate polymer (PS @ UTi) was prepared through in-situ reaction between sulfonated polystyrene microspheres coated tetrabutyl titanate and urushiol. The resultant PS @ UTi was characterized by scanning electron microscope and transmission electron microscope. Results indicated that the PS @ UTi with the excellent properties of raw lacquer was synthesized. The shell thickness of UTi coated on PS was tunable by changing the sulfonation time.

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34-38

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June 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] C.J. Serpell, J. Cookson, D. Ozkaya, P.D. Beer, Core @ shell bimetallic nanoparticle synthesis via anion coordination, Nat. Chem. 3 (2011) 478-483.

DOI: 10.1038/nchem.1030

Google Scholar

[2] K. Zhang, Y. Xiang, X. Wu, L. Feng, W. He, J. Liu, W. Zhou, S. Xie, Enhanced Optical Responses of Au @ Pd Core/Shell Nanobars, Langmuir. 25 (2008) 1162-1168.

DOI: 10.1021/la803060p

Google Scholar

[3] J.A. Czaban, D.A. Thompson, R.R. LaPierre, GaAs Core−Shell Nanowires for Photovoltaic Applications, Nano. Lett. 9 (2008) 148-154.

DOI: 10.1021/nl802700u

Google Scholar

[4] V. Salgueiriño-Maceira, M.A. Correa-Duarte, Increasing the Complexity of Magnetic Core/Shell Structured Nanocomposites for Biological Applications, Adv. Mater. 19 (2007) 4131-4144.

DOI: 10.1002/adma.200700418

Google Scholar

[5] M. Zhu, C. Wang, D. Meng, G. Diao, In situ synthesis of silver nanostructures on magnetic Fe3O4 @ C core–shell nanocomposites and their application in catalytic reduction reactions, J. Mater. Chem. A. 1 (2013) 2118-2125.

DOI: 10.1039/c2ta00669c

Google Scholar

[6] Q.H. Chen, L.H. Zheng, B.L. Chen, J.H. Lin, Scalable synthesis of TiO2–Ag Janus composite particles, Eur. Polym. J. 49 (2013) 2610-2616.

DOI: 10.1016/j.eurpolymj.2013.06.003

Google Scholar

[7] Q.H. Chen, B.L. Chen, L.H. Zheng, J.H. Lin, Preparation of Polyaniline/Polystyrene Janus Composite Particles, Chem. J. Chinese Univ. 34 (2013) 1788-1793.

Google Scholar

[8] R. Ghosh Chaudhuri, S. Paria, Core/shell nanoparticles: classes, properties, synthesis mechanisms, characterization, and applications, Chem. Rev. 112 (2012) 2373-2433.

DOI: 10.1021/cr100449n

Google Scholar

[9] J.R. Xia, J.H. Lin, Y.L. Xu, Q.H. Chen, On the UV-induced polymeric behavior of Chinese lacquer, ACS Appl. Mater. Interfaces. 3 (2011) 482-489.

DOI: 10.1021/am1010578

Google Scholar

[10] J.R. Xia, Y.L. Xu, J.H. Lin, B.H. Hu, A facile approach to imbed PbS nanocrystal in UV cured polyurushiol matrix, Mater. Lett. 63 (2009) 1499-1501.

DOI: 10.1016/j.matlet.2009.03.055

Google Scholar

[11] X.L. Zheng, J.B. Weng, B.H. Hu, X.Z. Lv, D.L. Meng, A.S.C. Chan, Fabrication of a stable superhydrophobic film constructed by poly(vinylpyrrolidone)/poly(urushiol)-CuS through layer-by-layer assembly, Mater. Chem. Phys. 130 (2011) 1054-1060.

DOI: 10.1016/j.matchemphys.2011.08.032

Google Scholar

[12] Q.H. Chen, J.H. Lin, Characterization and Properties of Urushiol-praseodymium Polymer, Chemistry and Industry of forest products. 26 (2006) 19-22.

Google Scholar

[13] B.H. Hu, W.D. Chen, J.H. Lin, The synthesis of urushiol titanium chelate polymers and their structural characteristics, Chinese journal of polymer science. 11 (1993) 198-203.

Google Scholar

[14] Z.Z. Yang, D. Li, J.H. Rong, W.D. Yan, Z.W. Niu, Opal Hydrogels Derived by Sulfonation of Polystyrene Colloidal Crystals, Macromol. Mater. Eng. 287 (2002) 627-633.

Google Scholar

[15] Z.Z. Yang, Z.W. Niu, Y.F. Lu, Z.B. Hu, C.C. Han, Templated Synthesis of Inorganic Hollow Spheres with a Tunable Cavity Size onto Core–Shell Gel Particles, Angew. Chem. Int. Ed. 42(2003) 1943-(1945).

DOI: 10.1002/anie.200250443

Google Scholar