Fabrication and Properties of Composites of Linear Polyacrylamide and Functionalized Carbon Nanotubes

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Abstract:

Polyacrylamide (PAM) was chemically anchored to the surface of multi-walled carbon nanotubes (MWCNTs) by atom transfer radical polymerization (ATRP) of acrylamide (AM). It started from the functional groups such as –COOH on the sidewall of MWCNTs, which derived from the oxidation of carbon nanotubes. FT-IR and 1H NMR results shown that the multi-walled carbon nanotubes grafted PAM (MWCNT-g-PAM) have been successfully carried out. The MWCNT-g-PAM showed different relative weight loss kinetics with PAM determined by thermal gravimetric analysis (TGA). The transmission electron microscopy (TEM) shown that the PAM grafted polymer was wrapped on the surface of carbon nanotubes.

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12-16

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June 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] C.A. Dyke, J.M. Tour, Solvent-free functionalization of carbon nanotubes, J. Am. Chem. Soc. 125, (2003) 1156-1157.

DOI: 10.1021/ja0289806

Google Scholar

[2] Y. Jeong, J. Kim, G.W. Lee, Optimizing functionalization of multiwalled carbon nanotubes using sodium lignosulfonate. Colloid Polymer Science 288 (2010) 1-6.

DOI: 10.1007/s00396-009-2127-8

Google Scholar

[3] C. Ma, W. Zhang, Y. Zhu, L. Ji, R. Zhang, N. Koratkar, J. Liang, Alignment and dispersion of functionalized carbon nanotubes in polymer composites induced by an electric field. Carbon 46 (2008) 706-720.

DOI: 10.1016/j.carbon.2008.01.019

Google Scholar

[4] S. Ravindran, S. Chaudhary, B. Colburn, M. Ozkan, C.S. Ozkan, Covalent Coupling of Quantum Dots to Multiwalled Carbon Nanotubes for Electronic Device Applications, Nano Lett. 3 (2003) 447-453.

DOI: 10.1021/nl0259683

Google Scholar

[5] Z. Wang, G. Luo, J. Chen, et al. Carbon nanotubes as separation carrier in capillary electrophoresis, Electrophoresis. 24, (2003), 4181-4188.

DOI: 10.1002/elps.200305575

Google Scholar

[6] C. Gao, YZ. Jin, H. Kong, RLD. Whitby, SFA. Acquah, GY. Chen, Polyurea-functionalized multiwalled carbon nanotubes: synthesis, morphology, and Raman spectroscopy, J. Phys. Chem. B. 109 (2005), 11925-11932.

DOI: 10.1021/jp051642h

Google Scholar

[7] H Tsuji, M Ogiwara, SK Saha, T Sakaki, Enzymatic, alkaline, and autocatalytic degradation of poly(L-lactic acid): effects of biaxial orientation, Biomacromolecules. 7, (2006), 380-387.

DOI: 10.1021/bm0507453

Google Scholar

[8] S Banerjee, SS. Wong, Structural characterization, optical properties, and improved solubility of carbon nanotubes functionalized with wilkinson's catalyst, J. Am. Chem. Soc. 124 (2002), p.8940.

DOI: 10.1021/ja026487o

Google Scholar

[9] D. Zhou, LP. Yang, RM. Yang, WH. Song, SH. Peng, YM. Wang. Novel quasi-interpenetrating network/functionalized multi-walled carbon nanotubes double-network composite matrices for DNA sequencing by CE, Electrophoresis. 29, (2008), pp.4637-4645.

DOI: 10.1002/elps.200700925

Google Scholar

[10] S. Qin, D. Qin, WT. Ford, et al. Polymer Brushes on Single-Walled Carbon Nanotubes by Atom Transfer Radical Polymerization of n-Butyl Methacrylate, J. Am. Chem. Soc. 126, (2004), 170-176.

DOI: 10.1021/ja037937v

Google Scholar

[11] RM. Yang, YM. Wang, XG. Wang, et al. Synthesis of poly(4-vinylpyridine) and block copoly (4-vinyipyridine-b-styrene) by atom transfer radical polymerization using 5, 5, 7, 12, 12, 14-hexamethyl-1, 4, 8, 11-tetraazamacrocycoltetradecane as ligand, Eur. Polym. J. 39, (2003).

DOI: 10.1016/s0014-3057(03)00070-3

Google Scholar

[12] H. Kong, C. Gao, D. Yan, Controlled Functionalization of multiwalled carbon nanotubes by in situ atom transfer radical polymerization, J. Am. Chem. Soc. 126, (2004), 412-413.

DOI: 10.1021/ja0380493

Google Scholar

[13] X. L. Wu, P. Liu, Poly(vinyl chloride)-grafted multi-walled carbon nanotubes via Friedel-Crafts alkylation, eXPRESS Polymer Letters, 4, (2010) 723-728.

DOI: 10.3144/expresspolymlett.2010.87

Google Scholar