Electrochemical Performances of the Binary Solvent Electrolytes with Lithium Bis(Oxalate)Borate

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Abstract. Lithium bis(oxalato)borate (LiBOB) is a promising salt for lithium ion batteries. The electrochemical behaviors of tetramethylene sulfone (TMS) / dimethyl sulfite (DMS) with different volume ratios of 1:2, 1:1, and 2:1 with 0.7 mol L-1 LiBOB salt are investigate in this work. Although the proportion of different solvents show different electrochemical performance, both of the LiBOB-based electrolytes show high oxidation potentials (> 5.5 V), and excellent film-forming characteristics.

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Advanced Materials Research (Volumes 953-954)

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1031-1034

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June 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] T. Nagaura, K. Tozawa, Prog. Batteries Solar Cells, vol. 9 (1990), p.209.

Google Scholar

[2] C. Korepp, W. Kern and E. A. Lanzer, J. Power Sources, vol. 174 (2007), p.387.

Google Scholar

[3] S. S. Zhang, J. Power Sources, vol. 163 (2006), p.567.

Google Scholar

[4] C. Korepp, W. Kern and E. A. Lanzer, J. Power Sources, vol. 174 (2007), p.628.

Google Scholar

[5] P. Ping, Q.S. Wang and J.H. Sun, Journal of Power Sources, vol. 96 (2011), p.776.

Google Scholar

[6] F. Azeez, P.S. Fedkiw, J. Power Sources, vol. 195 (2010), p.7627.

Google Scholar

[7] K. Xu, S.S. Zhang and B.A. Poese, Solid-State Lett, vol. 5 (2002), p. A259.

Google Scholar

[8] K. Xu, S.S. Zhang and T.R. Jow, Electrochem. Solid-State Lett, vol. 5 (2002), p. A26.

Google Scholar

[9] K. Xu, S.S. Zhang and T.R. Jow, Electrochem. Solid-State Lett, vol. 6 (2003), p. A117.

Google Scholar

[10] M. Wachtler, M. Wohlfahrt-Mehrens and S. Ströbele, J. Applied Electrochemistry, vol. 36 (2006), p. (1999).

Google Scholar

[11] B.T. Yu, W.H. Qiu and F.S. Li, Electrochem. Solid-State Lett, Vol. 9 (2006), p. A1.

Google Scholar

[12] S.Y. Li, P.H. Ma and S. T. Song, Russ. J. Electrochem, Vol. 44 (2008), p.1144.

Google Scholar