Investigation of Lithium Difluoro (Sulfato) Borate as a Salt of Electrolyte for High-Temperature Lithium-Ion Batteries

Article Preview

Abstract:

Lthium difluoro (sulfato) borate (LiBF2SO4) is a prospecting salt for electrolyte of lithium-ion batteries. The effect of LiBF2SO4 salt on conductivity, charge-discharge capacities, temperature performance, cycling life and storage life at 60 °C is investigated. In graphite half cells at 60 °C, LiBF2SO4-ethylene carbonate (EC)/ dimethyl carbonate (DMC) electrolyte favourably facilitates the formation of a thermal stable, effective and conductive interface film on the surface of carbonaceous anode. Besides, in LiCoO2 half cells at 60 °C, the electrolyte containing the novel salt exerts several advantages, such as stable cycling performance, and good capacity retention performance.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 953-954)

Pages:

1049-1052

Citation:

Online since:

June 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] J. M. Tarascon, M. Armand, Nature, 2001, vol. 414, pp.359-367.

Google Scholar

[2] Z. H. Li, Q. L. Xia, L. L. Liu, G. T. Lei, Q. Z. Xiao, D. S. Gao, X. D. Zhou, Electrochim. Acta, 2010, vol. 56, pp.804-809.

Google Scholar

[3] J. Arai, T. Yamaki, S. Yamauchi, T. Yuasa, T. Maeshima, T. Sakai, M. Koseki, T. Horiba, J. Power Sources, 2005, vol. 146, pp.788-792.

DOI: 10.1016/j.jpowsour.2005.03.087

Google Scholar

[4] Z. H. Chen, K. Amine, J. Electrochem. Soc, 2006, vol. 153, p. A1221-A1225.

Google Scholar

[5] J. Lui, A. Chen, S. Busking, K. Amine, Electrochem. Commun, 2007, vol. 9, pp.475-479.

Google Scholar

[6] S.Y. Li, W. Zhao, Y.Y. Zhao, X.P. Li, X.L. Cui, RSC ADV. DOI: 10. 1039/C3RA41311J.

Google Scholar

[7] S. Y. Li, W. Zhao, X. L. Cui, H. M. Zhang, X. X. Wang, W. X. Zhong, H. X. Feng, H. N. Liu, Electrochim. Acta, (2014).

Google Scholar