Preparation and Properties of Thiol-Ene UV-Curable Fluorinated Emulsion

Xiu Zhen Hu; Hua Yun Cheng; Wen Hua Deng; Chang Qing Fu

doi:10.4028/www.scientific.net/AMR.960-961.138

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 960-961Preparation and Properties of Thiol-Ene UV-Curable...

Preparation and Properties of Thiol-Ene UV-Curable Fluorinated Emulsion

Abstract:

Single electron transfer living radical emulsion polymerization (SET-LRP) of allyl methacrylate (AMA) coupled with 2,2,3,4,4,4-hexafluorobutyl methacrylate (HFBA) was investigated in the presence of Cu(0)/N,N,N’,N’’,N’’-pentamethyldiethylenetriamine (PMDETA) as catalyst and ethyl 2-bromoisobutyrate (EBiB) as initiator. Solid content of the emulsion and the amount of the catalyst, initiator and emulsifier were discussed for the optimal reaction conditions. Then, the emulsion was combined with thiol capped polyurethane (SHPU) under UV to form the UV curable fluorinated films. Mechanical properties and contact angle of the UV cured films were studied.

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Periodical:

Advanced Materials Research (Volumes 960-961)

Pages:

138-142

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.960-961.138

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Online since:

June 2014

Authors:

Xiu Zhen Hu, Hua Yun Cheng, Wen Hua Deng, Chang Qing Fu*

Keywords:

Fluorinate, SET-LRP, Thiol-ene, UV Curable

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* - Corresponding Author

References

[1] M Kamigaito, T Ando, M Sawamoto. Chem. Rev. Vol. 101(2001), p.3689.

Google Scholar

[2] V Percec, T Guliashvili, J S Ladislaw, A Wistrand, A Stjerndahl, M J Sienkowska, M J Monteiro, and S Sahoo. J. Am. Chem. Soc. Vol. 128(2006), p.14156.

DOI: 10.1021/ja065484z

Google Scholar

[3] N H Nguyen, B M Rosen, G Lligadas, V Percec. Macromolecules Vol. 42(2009), p.2379.

Google Scholar

[4] B M Rosen, V Percec. J. Polym. Sci., Part A: Polym. Chem. Vol. 45(2007), p.4950.

Google Scholar

[5] M J Monteiro, T Guliashvili, V Percec. J. Polym. Sci., Part A: Polym. Chem. Vol. 45(2007), p.1835.

Google Scholar

[6] N H Nguyen, J Kulis, H J Sun, Z Jia, B Beusekom, M E Levere, D A Wilson, M J Monteiro, V Percec. Polym. Chem. Vol. 4(2013), p.144.

DOI: 10.1039/c2py20782f

Google Scholar

[7] N H Nguyen, B M Rosen, V Percec. J. Polym. Sci., Polym. Chem. Vol. 48(2010), p.1752.

Google Scholar

[8] G Lligadas, V Percec. J. Polym. Sci., Polym. Chem. Vol. 46(2008), p.2745.

Google Scholar

[9] N H Nguyen, B M Rosen, X Jiang, S Fleischmann, V Percec. J. Polym. Sci., Polym. Chem. Vol. 47(2009), p.5577.

Google Scholar

[10] C Q Fu, H B Liu, Z Chen, C J Cheng, L Shen. Polyurethane Industry. Vol. 27(2012), p.5.

Google Scholar