The Thermal Properties of Unsaturated Polyester Resin Treated with Intumescent Flame Retardants

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Abstract:

A novel cheap macromolecular intumescent flame retardant (IFR), was synthesized. Unsaturated polyester resin (UPR) was modified with IFR to get the flame retardant UPR, whose flammability and burning behavior were characterized by limiting oxygen index (LOI). 22.7% of weight of IFR was doped into UPR to get 28.5 of LOI. The thermal properties of epoxy resins containing IFR were investigated with thermogravimetry (TG). Activation energy for the decomposition of samples was obtained using Kissinger equation. The resultant data show that for UPR containing IFR, compared with UPR, IFR decreased weight loss, thermal stability, increased the char yield, which shows that IFR can catalyze decomposition and carbonization of UPR.

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52-55

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June 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] S Bourbigot, M Le Rras, S Duquesne, M Rochery: Macromolecular Materials and Engineering, Vol. 289(2004), p.499.

Google Scholar

[2] Q Wu, B Qu: Polymer Degradation and Stability, Vol. 74(2001), p.255.

Google Scholar

[3] C. F. Cullis, M. M. Hirschler: Eur. Polym. J. Vol. 20(1984), p.53.

Google Scholar

[4] M Gao, W Wu, Y Yan: J. Therm. Anal. Cal. Vol. 95(2009), p.605.

Google Scholar

[5] M Gao, S S Yang: J. Appl. Polymer Sci. Vol. 115(2010), p.2346.

Google Scholar

[6] Oertel, G. Polyurethane Handbook; Hanser: New York, (1994).

Google Scholar

[7] B. Youssef, B. Mortaigne, M. Soulard and J. M. Saiter, Therm. Anal. Cal., 90 (2007), 489.

Google Scholar

[8] B. K. Kandola, A. R. Horrocks, D. Price, and G. V. Coleman, J. Macromal. Sci., Rev. Macromol. Chem. Phys. C36 (4) (1996), 721.

Google Scholar