Synthesis of Al-Al3Ti In Situ Metal Matrix Composites by Salt Route and Evaluation of their Mechanical Properties

Article Preview

Abstract:

Current work, aims at preparation and characterization of Al-Al3Ti in-situ metal matrix composites with varying percentage of in-situ Al3Ti (3 and 5%) reinforcement. The composites were prepared by the salt route involving reaction of commercial purity aluminum (99.7%) and potassium titanium flourate halide (K2TiF6) salt at a reaction temperature of 800°C and with 60min. holding time. The prepared composites were subjected to microstructural studies using Scanning Electron Microscope. Further, the work aims at evaluating mechanical properties of the prepared composites as per ASTM standards. Microstructural characterization using SEM revealed blocky morphology of Al3Ti intermetallics with fairly homogeneous distribution. Insitu Al-Al3Ti composites have shown better mechanical properties when compared to the unreinforced Al matrix.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 984-985)

Pages:

280-284

Citation:

Online since:

July 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Faith, T.; Ayer, K.; Ahmet, K.; Mustafa, C.; Isil, K. Processing and microstructural characterization of AA1070 and AA6063 matrix B4Cp reinforced composites. Materials and Design 2010, 31, S87-S91.

DOI: 10.1016/j.matdes.2009.11.064

Google Scholar

[2] Canakci, A. Microstructure and abrasive wear behaviour of B4C particle reinforced 2014 Al matrix composites. Journal of Material Science 2011, 46(08), 2805-2813.

DOI: 10.1007/s10853-010-5156-2

Google Scholar

[3] Kevorkijan, V.; Skapin, S.D. Mg/B4C composite with a high volume fraction of fine ceramic reinforcement. Materials and Manufacturing Processes 2009, 24, 1337-1340.

DOI: 10.1080/10426910902997076

Google Scholar

[4] Kwang-Min L, In-Hyung M. High temperature performance of dispersion-strengthened Al-Ti alloys prepared by mechanical alloying. Materials Science and Engineering A, 1994, 185: 165–171.

DOI: 10.1016/0921-5093(94)90940-7

Google Scholar

[5] Birol Y. Analysis of the response to thermal exposure of Al/K2TiF6 powder blends. Journal of Alloys and compounds, 2008, 455(1-2): 164–167.

DOI: 10.1016/j.jallcom.2007.01.021

Google Scholar

[6] Nofar M, Madaah Hosseini H R, Kolagar-Daroonkolaie N. Fabrication of high wear resistant Al/Al3Ti metal matrix composite by in situ hot press method. Materials and Design, 2009, 30: 280–286.

DOI: 10.1016/j.matdes.2008.04.071

Google Scholar

[7] Srinvasan S, Chen S R, Schwarz R B. Synthesis of Al-Al3Titwo phase alloys by mechanical alloying. Materials Science and Engineering A, 1992, 153: 691–698.

Google Scholar

[8] Feng C F, Froyen L. Formation of Al3Ti and Al2O3 from an Al-TiO2 system for preparing in-situ aluminum matrix composites. Composites: Part A, 2000, 31: 385–390.

DOI: 10.1016/s1359-835x(99)00041-x

Google Scholar

[9] Tjong S C, Tam K F, Wu S Q. Thermal cycling characteristics of in situ Al-based composites prepared by reactive hot pressing. Composites Science and Technology, 2003, 63: 89–97.

DOI: 10.1016/s0266-3538(02)00200-2

Google Scholar

[10] Wu J M, Li Z Z. Contributions of the particulate reinforcement to dry sliding wear resistance of rapidly solidified Al-Ti alloys. Wear, 2000, 244: 147–153.

DOI: 10.1016/s0043-1648(00)00452-x

Google Scholar

[11] Wu J M, Zheng S L, Li Z Z. Thermal stability and its effects on the mechanical properties of rapidly solidified Al-Ti alloys. Materials Science and Engineering A, 2000, 289: 246–254.

DOI: 10.1016/s0921-5093(00)00886-8

Google Scholar

[12] Wang X, Jha A, Brydson R. In situ fabrication of Al3Ti particle reinforced aluminum alloy metal-matrix composites. Materials Science and Engineering A, 2004, 364: 339–345.

DOI: 10.1016/j.msea.2003.08.049

Google Scholar

[13] Yu S R, Feng H K, Li Y L. A novel method for preparing Al matrix surface composites. Journal of Alloys and Compounds, 2008, 457: 404–407.

DOI: 10.1016/j.jallcom.2007.02.125

Google Scholar

[14] Watanabe Y, Eryu H, Matsuura K. Evaluation of three-dimensional orientation of Al3Ti platelets in Al -based functionally graded materials fabricated by a centrifugal casting technique. Acta Materialia, 2001, 49: 775–783.

DOI: 10.1016/s1359-6454(00)00384-0

Google Scholar

[15] Sato H, Murase T, Fujii T, et al. Formation of a wear-induced layer with nanocrystalline structure in Al-Al3Ti functionally graded material. Acta Materialia, 2008, 56: 4549–4558.

DOI: 10.1016/j.actamat.2008.05.012

Google Scholar

[16] Das K, Narnaware L K. Synthesis and characterization of Al-4. 5%Cu/Al3Ti composites: microstructure and ageing behaviors. Materials Science and Engineering A, 2008, 497: 25-30.

DOI: 10.1016/j.msea.2008.06.014

Google Scholar

[17] Watanabe Y, Yamanaka N, Fukui Y. Wear behavior of Al-Al3Ti composites manufactured by a centrifugal method, Metallurgical and Materials Transactions A, 1999, 30: 3253–3261.

DOI: 10.1007/s11661-999-0235-1

Google Scholar

[18] Sequeira P D, Watanabe Y, Fukui Y. Backward extrusion of Al-Al3Ti functionally graded materials: volume fraction gradient and anisotropic orientation of Al3Ti platelets. Scripta Materialia, 2005, 53: 687–692.

DOI: 10.1016/j.scriptamat.2005.05.029

Google Scholar

[19] Watanabe Y, Nakamura T. Microstructures and wear resistance of hybrid Al-(Al3Ti+Al3Ni) FGM fabricated by a centrifugal method. Intermetallics, 2001, 9: 33–43.

DOI: 10.1016/s0966-9795(00)00086-8

Google Scholar

[20] Watanabe Y, Kawamoto A, Matsuda K. Particle size distributions in functionally graded materials fabricated by the centrifugal solid-particle method. Composites Science and Technology, 2002, 62: 881–888.

DOI: 10.1016/s0266-3538(02)00023-4

Google Scholar

[21] Auradi, V.; Kori, S.A. Influence of reaction temperature on the manufacturing of Al-3Ti and Al-3B master alloys. Journal of Alloys and Compounds, 2008, 453, 147-156.

DOI: 10.1016/j.jallcom.2006.11.119

Google Scholar

[22] Chen Tijun, Li Jian and Hao Yuan, Casting fabrication of in situ Al3Ti-Al composites and their wear behaviors, Research and Development, China Foundry, 2009, 319-327.

Google Scholar