The Preparation and Characterization of Polybenzoxazole Copolymerized with Multiwalled Carbon Nanotube via Direct Friedel-Crafts Acylation

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Abstract:

Multiwalled carbon nanotube (MWCNT) was subjected a copolymerization reaction with 4, 6-diaminoresorcinol salt (DAR•2HCl) and terephthalic acid (TA) in polyphosphoric acid (PPA) by Friedel-Crafts acylation reaction without any acid treatment or modification. The structure and morphology of the as-prepared poly (p-phenylene benzobisoxazole) (PBO)/MWCNT nanocomposites were characterized by X-ray diffraction (XRD) and scanning electronic microscope (SEM). The SEM images indicated that MWCNTs can disperse in PBO matrix uniformly without agglomeration and MWCNTs have been introduced into PBO matrix by covalent bonding via Friedel-Crafts acylation between MWCNTs and TA.

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Advanced Materials Research (Volumes 989-994)

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560-563

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July 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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DOI: 10.1021/ma0205055

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