The Basic Investigation on Catalytic Oxidation of Mine Gas to Methanol in Liquid Phase

Feng Xu; Chuang Li; Shao Yang Jia

doi:10.4028/www.scientific.net/AMR.997.51

Paper Titles

Synthesis of Aminotriacetic Acid Intercalated MgAl-Layered Double Hydroxides and its Selective IR Absorption Properties
p.33

Optimization of Lactose Content in the Row Milk by Colorimetry via Response Surface Methodology
p.38

Synthesis, Structure Characterization and Photocatalytic Property of a Supramolecular Compound: [Co(en)₃]₂[H₃PMo₈V₆O₄₂]∙5H₂O
p.43

Effect of Solvent on Ethanolysis Reaction of Natrual Soybean Phosphatidylcholine
p.47

The Basic Investigation on Catalytic Oxidation of Mine Gas to Methanol in Liquid Phase
p.51

Influence of the Composition and Preparation Methods of the Catalysts for Methane Combustion
p.57

The Development of New Active Gelled Acid and the Practical Application
p.62

Optimization Design Method for Production Parameters of Submersible Pump Well of Polymer Flooding
p.69

L-α-Glycerophosphocholine from Natural Lecithin via Transesterification Catalyzed by Propylamine
p.73

HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 997The Basic Investigation on Catalytic Oxidation of...

The Basic Investigation on Catalytic Oxidation of Mine Gas to Methanol in Liquid Phase

Abstract:

A set of experimental system was self-designed and made for liquid phase catalytic oxidation of gas to methanol. It was used to investigate the impacts of catalyst and reaction conditions on catalytic oxidation of gas to methanol in acetic acid solution, and to analyze its reaction mechanism. It has been showed that the yield of the methanol is 1840 μmol under the catalysis of 0.5 g of 0.5% Pd-CuPc/Y and the following conditions: CH3COOH:H2O = 4:1 (v/v), 1000 μmol of p-benzoquinone; reaction time, 3 h; reaction temperature, 150°C; gas composition, 2.5MPa CH4+0.4MPaO2 +0.4MPa N2; in acetic acid solution, catalytic oxidation of mine gas to methanol follows mechanisms of electrophilic substitution and oxidation of reactive oxygen species (ROS).

You might also be interested in these eBooks

Frontiers of Chemical Engineering, Metallurgical Engineering and Materials III

View Preview

Info:

Periodical:

Advanced Materials Research (Volume 997)

Pages:

51-56

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.997.51

Citation:

Cite this paper

Online since:

August 2014

Authors:

Feng Xu*, Chuang Li, Shao Yang Jia

Keywords:

Catalytic Oxidation, Liquid Phase, Mechanism, Methanol, Mine Gas

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] X. Feng, Z. Lihua: Journal of Heilongjiang Institute of Science and Technology. Vol. 22(2012), pp.14-16(in Chinese).

Google Scholar

[2] X. Feng, Z. Xiaopeng, Z. Lihua, W. Jue: Journal of Heilongjiang Institute of Science and Technology. Vol. 22(2012), pp.558-561(in Chinese).

Google Scholar

[3] Z. Lihua, X. Feng, B. Yewu, S. Bin: Chin.J. Geochem. Vol. 33(2014), pp.183-186.

Google Scholar

[4] Yoshihiko I., Toshikazu H., Takeo S.: J. Org. Chem. Vol. 43(1978), pp.1011-1013.

Google Scholar

[5] Porth S., Bats J. W., Trauner D., Giester G., Mulzer J.: Angew. Chem. Int. Ed. Vol. 38(1999), p.2015-(2016).

Google Scholar

[6] A. Zengjian, P. Xiulian, L. Xiumei: Journal of Natural Gas Chemistry. Vol. 17(2008), pp.120-124.

Google Scholar

[7] Bergstad K., Grennberg H., Bäckvall J. E.: Organometallics. Vol. 17(1998), pp.45-50.

Google Scholar

[8] Bosch E., Rathore R., Kochi J. K.: J. Org. Chem. Vol(59)1994, pp.2529-2536.

Google Scholar

[9] Z. Lihua, X. Feng, W. Jue: Research Journal of Chemistry and Environment. Vol. 17(2013), pp.151-155.

Google Scholar

[10] Z. Lihua, X. Feng, W. Jue: Chin.J. Geochem. Vol. 41(2013), pp.985-990(in Chinese).

Google Scholar

[11] X. Feng, Z. Lihua: Research Journal of Chemistry and Environment. Vol. 16(2012), pp.122-126.

Google Scholar

[12] X. Feng, Z. Lihua, H. Fengcai, S. Bin: Chin. J. Geochem. Vol. 40(2012), pp.1098-1102(in Chinese).

Google Scholar

[13] X. Feng, L. Chuang, W. Jue, J. Shaoyang, Z. Xiaopeng, Z. lihua: Journal of Heilongjiang Institute of Science and Technology. Vol. 24(2014), pp.48-52(in Chinese).

Google Scholar

[14] A. E. Shilov, G. B. Shulpin: Chem. Rev. Vol. 97(1997), pp.2879-2932.

Google Scholar