Synthesis, Structure Characterization and Photocatalytic Property of a Supramolecular Compound: [Co(en)3]2[H3PMo8V6O42]∙5H2O

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Abstract:

A new supramolecular compound, [Co (en)3]2[H3PMo8V6O42]∙5H2O (1) has been hydrothermally synthesized and structurally characterized by the elemental analysis, IR and single crystal X-ray diffraction. Compound 1 consists of [Co (en)2]2+ transition metal coordination fragment, [H3PMo8V6O42]4- building blocks and crystal water molecules, which are linked together via hydrogen-bonding interactions to form a new 3-D supramolecular networks. The degradation of methylene blue (MB) under UV-vis irradiation with 1 as the heterogeneous photocatalyst has been investigated, showing a good photocatalytic property of 1 for MB degradation.

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43-46

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August 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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