Synthesis, Photophysical Properties and Photoinduced Intermolecular Electron Transfer of a Novel Aryl Benzyl Ester Dendritic Axially Substituted Silicon (IV) Phthalocyanine

Xiu Qin Chen; Dong Dong Ma; Su Juan Pan; Yu Hua Wang; Kui Zhi Chen; Hong Qin Yang; Yi Ru Peng

doi:10.4028/www.scientific.net/AMR.998-999.99

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 998-999Synthesis, Photophysical Properties and...

Synthesis, Photophysical Properties and Photoinduced Intermolecular Electron Transfer of a Novel Aryl Benzyl Ester Dendritic Axially Substituted Silicon (IV) Phthalocyanine

Abstract:

An aryl benzyl ester dendritic axially substituted silicon (IV) phthalocyanine, a di-{3,5-di-(4-methoxycarbonyl group benzyloxy) benzyloxy) benzyloxy} axially substituted silicon (IV) phthalocyanine (DSiPc) was synthesized. Its structure was characterized by elemental analysis, ¹H NMR, IR and ESI-MS. The photophysical property of DSiPc was studied by steady and time-resolved spectroscopic methods. The steric hindrance of dendritic structure can reduced the aggregation efficiently. The photoinduced intermolecular electron transfer between this novel macromolecule and benzoquinone was studied. The results showed that the fluorescence emission of this dendritic phthalocyanine could be quenched by BQ. Therefore, this novel dendritic phthalocyanine was an effective new electron donor and transmission complex could be used as a potential artificial photosynthesis system.

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Advanced Materials Research (Volumes 998-999)

Pages:

99-102

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.998-999.99

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Online since:

July 2014

Authors:

Xiu Qin Chen*, Dong Dong Ma, Su Juan Pan, Yu Hua Wang, Kui Zhi Chen, Hong Qin Yang, Yi Ru Peng

Keywords:

Dendimer, Electron Transfer, Photophysical Property, Silicon Phthalocyanine

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References

[1] K. Plaetzer, B. Krammer, J. Berlanda, F. Berr, T. Kiesslich: Lasers. Med. Sci. 24(2) (2006), p.259–268.

DOI: 10.1007/s10103-008-0539-1

Google Scholar

[2] F. Dumoulin, M. Durmuş, V. Ahsen, T. Nyokong: Coord. Chem. Rev. 254(23) (2010), p.2792–2847.

DOI: 10.1016/j.ccr.2010.05.002

Google Scholar

[3] S.W. Li , T. Aida: Chemical reviews 109(11) (2009), pp.6047-6076.

Google Scholar

[4] Z. Bıyıklıoğlu: Dyes and Pigments 99(1) (2013), pp.59-66.

Google Scholar

[5] B. Çoşut, S. Yeşilot , M. Durmuş, A. Kılıç, V. Ahsen: Polyhedron 29(2) (2010), pp.675-682.

DOI: 10.1016/j.poly.2009.09.035

Google Scholar

[6] M.K. Lowery, A.J. Starshak, J.N. Esposito, P.C. Krueger, M.E. Kenney: Inorg. Chem. 4(1) (1965), p.128.

Google Scholar

[7] D. D He , H. Zhang , Y. R Peng, et al. Chin. J. Org. Chem. 32(7) (2012), pp.1321-1326.

Google Scholar

[8] J.Y. Liu, X.J. Jiang, W.P. Fong, D.K.P. Ng: Organic Biomolecular Chemistry 6(24) (2008), pp.4560-4566.

Google Scholar

[9] B. Çoşut, S. Yeşilot, M. Durmuş, A. Kılıç, V. Ahsen: Polyhedron, 29(2) (2010), pp.675-682.

DOI: 10.1016/j.poly.2009.09.035

Google Scholar