Synthesis of Carbon Nanotubes by the Catalytic Decomposition of Methane

Abstract:

The influence of morphology of the support particles upon the nickel-catalyzed decomposition of methane into carbon nanotubes and hydrogen was explored using a thermogravimetric apparatus. High carbon nanotube yield was attained by the Ni catalysts supported on the glycothermally synthesized ZrO2 and Er3Ga5O12 particles, which had spherical shapes. Quite high carbon yield was also obtained by the Ni catalyst supported on spherical Al2O3 particles (Nanophase Tech. Corp.). It was concluded that the most important factor governing the carbon yield is the morphology of the catalyst support, which contributes to the internal pressure of carbon nanotubes thus determining their chemical potentials.

• Periodical: Advances in Science and Technology (Volume 48)
• Pages: 67-72
• DOI: https://doi.org/10.4028/www.scientific.net/AST.48.67
• Online since: October 2006
• Authors: Masashi Inoue, Kouta Asai, Yoshiyuki Nagayasu, Koji Takane, Eriko Yagasaki
• Keywords: Carbon Nanotube (CN), Catalyst Support, Glycothermal Synthesis, Methane Decomposition, Morpholoy, Nickel Catalyst

References

[1] J. Jia, Y. Wang, E. Tanabe, T. Shishido and K. Takehira: Microporous Mesoporous Mater. Vol. 57 (2003), p.283.

[2] A.M. Cassell, J.A. Raymakers, J. Kong and H. Dai: J. Phys. Chem. B Vol. 103 (1999), p.6484.

[3] Y. Zhang and K.J. Smith: Catal. Today Vol. 77 (2002), p.257.

[4] S. Takenaka, H. Ogihara and K. Otsuka: J. Catal. Vol. 208 (2002), 54.

[5] T.V. Choudhary, C. Sivadinarayana, C.C. Chusuei, A. Klinghoffer and D.W. Goodman: J. Catal. Vol. 199 (2001), p.9.

[6] Y. Nagayasu, A. Nakayama, S. Kurasawa, S. Iwamoto, E. Yagasaki and M. Inoue: J. Jpn. Petrol. Inst. Vol. 48 (2005), p.301.

DOI: 10.1627/jpi.48.301

[7] Y. Nagayasu, K. Asai, A. Nakayama, S. Iwamoto, E. Yagasaki and M. Inoue: J. Jpn. Petrol. Inst. Vol. 49 (2006), p.186.

DOI: 10.1627/jpi.49.186

[8] A. Nakayama, K. Asai, Y. Nagayasu, S. Iwamoto, E. Yagasaki and M. Inoue: J. Jpn. Petrol. Inst. in press.

[9] M. Inoue, H. Kominami and T. Inui: Appl. Catal. A General Vol. 97 (1993), p. L25.

[10] M. Inoue, T. Nishikawa, H. Otsu, H. Kominami and T. Inui: J. Am. Ceram. Soc. Vol. 81 (1998),. p.1173.

[11] M. Inoue: J. Phys.: Condens. Matter Vol. 16 (2004),. p. S1291.

[12] T. Takeguchi, S. Furukawa and M. Inoue: J. Catal. Vol. 202 (2001),. p.14.

[13] J. Rostrup-Nielsen and D. L. Trimm: J. Catal. Vol. 48 (1977), p.155.

[14] L.S. Lobo and D.L. Trimm: Nature (London) Vol. 234 (1971),. p.15.

[15] J. Rostrup-Nielsen: Catalysis-Science and Tecknolory Vol. 5, ed. by J.R. Anderson. M. Boudart, (Springer-Verlag, Berlin 1984), chap. 1.

[16] S.B. Sinnott, R. Andrews, D. Qian, A.M. Rao, Z. Mao, E.C. Dickey and F. Derbyshire: Chem. Phys. Lett. Vol. 315 (1999), p.25.

[17] J.W. Snoeck, G.F. Froment and M. Fowles: J. Catal. Vol. 169 (1997), p.240.

[18] M.A. Ermakova, D.Y. Ermakov and G.G. Kuvshinov: Appl. Catal. A General Vol. 201 (2000), p.61.

[19] F. Cataldo: Carbon Vol. 37 (1999), p.161.

[20] T. Jawhari, A. Roid and J. Casado: Carbon Vol. 33 (1995), p.1561.

[21] R.T.K. Baker, M.A. Barber, P.S. Harris, F.S. Feates and R.J. Waite: J. Catal. Vol. 26 (1972), p.51.

[22] A.J.H.M. Kock, P.K. Bokx, E. Boellaard, W. Klop and J.W. Geus: J. Catal. Vol. 96 (1985), p.468.

[23] R.T. Yang and J.P. Chen: J. Catal. Vol. 115, (1989), p.52.