An Innovative Hybrid Process Involving Plasma in a Cold Crucible Melter Devoted to the Futur Intermediate Level Waste Treatment: The SHIVA Technology

Abstract:

The cold crucible technology first developed for the treatment of the high level fission products can also be used for the direct treatment of intermediate level wastes. In this case, the wastes can be under the states of liquids or solids. The first experiments carried out for the direct treatment of ionic exchange resins emphasised the requirement of very high temperature on the surface of the glass. When this surface is to cold, the unperfected oxidation lead to a glass containing inclusion such as metallic compounds coming from the reduction of species contained in the waste. Thus, the quality of the glass could be not enough to meet with some specific requirements for long term storage. For few years, the Laboratory of the Innovative Processes has been studied the capability of a cold crucible to involved plasma torches ensuring the high temperature required for a complete oxidation of a large composition of waste. The developments and the assessment of different technological ways lead to build a cold crucible fitted with a bottom inductor together with twin plasma torches above the glass bath. This is the SHIVA process. The researches carried out on this innovative technology have shown the high efficiency of the combination for the treatment of a large variety of solid wastes. The oxidation is complete and the produced glass can be easily poured in a canister. This innovative process provides new perspective of treatment for a large variety of intermediate level waste stored on the ground of nuclear facilities.

• Periodical: Advances in Science and Technology (Volume 73)
• Pages: 148-157
• DOI: https://doi.org/10.4028/www.scientific.net/AST.73.148
• Online since: October 2010
• Authors: Florent Lemont, Patrice Charvin, Aldo Russello, Karine Poizot
• Keywords: Cold Crucible, Incineration Vitrification, Plasma Torch, Radioactive Waste (RAW), SHIVA

References

[1] Kwansik Choi, Cheon-Woo Kim, Jong Kil Park, Byoung Chul Park, Kyoung-Hwa Yang, SangWoon Shin, Pierre Brunelo and Thierry Flament: Transactions, SMiRT, Washington DC, August (2001).

[2] C.M. Jantzen D.K. Peeler, C.A. Cicero, Westingouse Savannh River Company, WSRC-MS-95- 0518 / CONF - 9504124.

[3] F. Lemont, S. Hugues, E. Meillot, High Temperature Materials and Processes, Vol. 27, n°5, (2008).

[4] F. Lemort, JP. Charvillat, Incineration of chlorinated organic nuclear waste: In situ substitution of phosphates for chlorides, ICEM'99 - September 26-30, 1999, Nagoya - Japon Gas Electrode Acoustic declogging device High voltage Dust migration Electrode Dust extraction.

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[95] [90] [85] [80] [75] Efficiency% Operating time (min).

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[95] [90] [85] [80] [75] Gas + Dust Standard tube Direct voltage Innovative electrode Direct voltage Innovative electrode Direct voltage + Pulse voltage Gas Electrode Acoustic declogging device High voltage Dust migration Electrode Dust extraction.

DOI: 10.3403/30229759

50 100 150 200 250 300 350 400 450 500 100.

[95] [90] [85] [80] [75] Efficiency% Operating time (min).

50 100 150 200 250 300 350 400 450 500 100.

[95] [90] [85] [80] [75] Gas + Dust Standard tube Direct voltage Innovative electrode Direct voltage Innovative electrode Direct voltage + Pulse voltage.