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HomeAdvances in Science and TechnologyAdvances in Science and Technology Vol. 75Synthesis of Fluorinated Organic and...

Synthesis of Fluorinated Organic and Organometallic Electroluminescent Materials: Tuning Emission in the Blue

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Abstract:

Functionalization with fluorine atoms represents a versatile structural modification to finely tune both the emission colour and the electronic properties of organic and organometallic electroluminescent compounds. This paper reports an overview of our systematic investigation on the design and synthesis of the fluorinated version of two important classes of materials for organic light emitting diodes (OLEDs), namely poly(arylenevinylene)s and phosphorescent phenylpyridine Iridium complexes. Synthetic pathways based on organometallic methodologies affording selectively fluorinated molecular structures will be discussed together with a summary of the effect of fluorination on the optical properties of the resulting materials. In particular we will highlight the possibilities offered by the organometallic methodologies as straightforward and resourceful tools to provide a wide series of fluorinated molecular architectures with high regio- and stereoselectivity, mild experimental conditions and good yields.

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Periodical:

Advances in Science and Technology (Volume 75)

Pages:

108-117

DOI:

https://doi.org/10.4028/www.scientific.net/AST.75.108

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Online since:

October 2010

Authors:

Gianluca M. Farinola, Francesco Babudri, Antonio Cardone, Omar Hassan Omar, Carmela Martinelli, Francesco Naso, Vita Pinto, Roberta Ragni

Keywords:

Electroluminescent Polymer, Organic Electroluminescence, Phosphorescent Ir Complex, Synthesis Of Organic Semiconductor

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© 2010 Trans Tech Publications Ltd. All Rights Reserved

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