Synthesis, Characterization and Luminescent Properties of New Coordination Polymers Based on p-tert-Butylcalix[4]Arene-Tetracarboxylic Acid and Lanthanide Cations

Bráulio Silva Barros; Carlos Alberto Fernandes de Oliveira; Joanna Kulesza; Severino Alves Júnior; Maria Bocheńska

doi:10.4028/www.scientific.net/AST.77.132

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HomeAdvances in Science and TechnologyAdvances in Science and Technology Vol. 77Synthesis, Characterization and Luminescent...

Synthesis, Characterization and Luminescent Properties of New Coordination Polymers Based on p-tert-Butylcalix[4]Arene-Tetracarboxylic Acid and Lanthanide Cations

Abstract:

A series of new coordination polymers based on p-tert-butylcalix[4]arene- tetracarboxylic acid with Eu3+ (1a), Tb3+ (1b) and Tm3+ (1c) were prepared by hydro and solvothermal methods. The obtained solid compounds were characterized by infrared and luminescence spectroscopy, powder X-ray diffraction, scanning electron microscopy and thermogravimetric analysis. The infrared curves and the x-ray diffraction patterns indicate that the same crystalline structure was obtained for all lanthanides.

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Periodical:

Advances in Science and Technology (Volume 77)

Pages:

132-137

DOI:

https://doi.org/10.4028/www.scientific.net/AST.77.132

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Online since:

September 2012

Authors:

Bráulio Silva Barros, Carlos Alberto Fernandes de Oliveira, Joanna Kulesza, Severino Alves Júnior, Maria Bocheńska

Keywords:

Calix[4]Arene-Tetracarboxylic Acid, Coordination Polymers, Hydrothermal Synthesis, Lanthanides, Solvothermal Synthesis

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