Heat-Treatment Processing for MnBi in High Magnetic Fields

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The phase diagram for MnBi was investigated in high fields up to 18 T at temperatures ranging from 300 to 730 K. We used the differential thermal analysis (DTA), in order to examine the equilibrium phase change of ferromagnetic MnBi by applying high magnetic fields. In particular, the first-order magnetic phase transition to the paramagnetic phase at the decomposition temperature Tt ~ 628 K for ferromagnetic MnBi was evaluated in fields up to 26 T. It was found that Tt increases with increasing magnetic fields at the rate of 2 K/T in low fields up to 18 T, and clearly deviates from the linear increase above 20 T. From a viewpoint of application, it is important that the decomposition of MnBi can be controlled by a magnetic field. As a result, Tt on the liquid phase line changes the amount of Mn content from 10 to 16.5at.% at 26 T, and the heat-treatment at 26 T improves the volume fraction of MnBi. Further, it is quite interesting to directly synthesize ferromagnetic MnBi from the liquid phase without the paramagnetic phase transformation.

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19-24

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September 2012

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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