Isotopic Exchange of Gaseous Oxygen with Mechanoactivated Manganese Oxides

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Abstract:

sotope exchange of oxygen 18О2 with oxides Mn2O3 and Mn3O4 was investigated in the temperature range of 300700°C. It was established that the content of the isotope O18 in mechanically activated powders was noticeably higher than in the initial ones. Already at relatively low annealing temperatures isotope exchange leads to nearly the maximum possible under the given conditions replacement of atoms 16O to 18O. The isotope exchange parameters connected with the processes at the boundaries of the particles of mechanoactivated powder and within their volume were determined.

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Defect and Diffusion Forum (Volumes 326-328)

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713-718

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April 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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